ORIGINAL_ARTICLE
A Method Based on Ultrasound-assisted Solidification of Floating Drop Microextraction Technique for the Spectrophotometric Determination of Curcumin in Turmeric Powder
A method based on the ultrasound-assisted solidification of floating drop microextraction technique was developed for the spectrophotometric and spectrofluorimetric determination of curcumin in turmeric powder. In this work a small volume of an organic solvent was floated on the surface of an aqueous solution. After sonication the organic solvent is solidified and separated. The effect of extraction parameters such as type and the volume of organic solvent, temperature, salt addition and exposure time, on the extraction recovery was investigated and optimized. Finally, the method droplet was used for the determination of analyte. Under the optimum extraction conditions, a linear range of 0.006–30 μg mL-1 and a relative standard deviation (RSD) of 2.72% for curcumin wasachieved. Limits of detection of 7 and 2 ng mL-1 curcumin was obtained for the spectrophotometric and spectrofluometric methods, respectively. The obtained results show that the application of this method can be successful for the analysis of curcumin in turmeric powder samples.
https://www.analchemres.org/article_40235_d38b28a2d158ffba117b4ddac6466d4e.pdf
2017-06-01
1
10
10.22036/abcr.2017.40235
curcumin
Solidification of floating drop microextraction
Spectrophotometriy
Spectrofluorimetry
Turmeric powder
Abbas
Afkhami
abbas.afkhami@gmail.com
1
Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran
LEAD_AUTHOR
Massoumeh
Pirdadeh-Beiranvand
ma.pirdade@yahoo.com
2
Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran
AUTHOR
Tayyebeh
Madrakian
madrakian@basu.ac.ir
3
Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran
AUTHOR
[1] C.R. Ireson, D.J.L. Jones, S. Orr, M.W.H. Coughtrie, D.J. Boocock, M.I. Williams, P.B. Farmer, W.P. Steward, A.J. Gescher, Biomarkers Prev. 11 (2002) 105.
1
[2] F. Zsila, Z. Bikadi, M. Simonyi, Biophys. Res. Commun. 301 (2003) 776.
2
[3] W. Lee, Ch. Loo, M. Bebawy, F. Luk, R. Mason, R. Rohanizadeh, Curr. Neuropharmacol. 11 ( 2013) 338.
3
[4] T. Hamaguchi, K. Ono, M. Yamada, CNS Neurosci. Ther. 16 (2010) 285.
4
[5] P. Manikandan, M. Sumitra, S. Aishwarya, BM. Manohar, B. Lokanadam, R. Puvanakrishnan, Biochem. Cell Biol. 36 (2004) 1967.
5
[6] L. Pari, D. Tewas, J. Eckel, Arch. Physiol. Biochem. 114 (2008) 127.
6
[7] SH. Shishodi, G. Sethi, B. B. Aggarwal, Ann. N. Y. Acad. Sci. 1056 (2005) 206.
7
[8] B. Hadi, M. Sanagi, H. Aboul-Enein, W. Ibrahim, Sh. Jamil, M. Mu’azu, Food Anal. Methods. 8 (2015) 2447-.
8
[9] M. Safdarian, P. Hashemi, M. Naderlou, J. Chromatogr. A. 1244 (2012) 14.
9
[10] M. Rahimi, P. Hashemi, F. Nazari, Anal. Chim. Acta., 826 (2014) 35.
10
[11] P. Kadam, Ch. Bhingare, R. Nikam, S. Pawar, Pharm. Methods. 4 (2013) 43.
11
[12] V. Kakkara, S. Singhb, D. Singlab, S. Sahwneyc, A. S. Chauhanc, G . Singhc, I. P. Kaura J. Chromatogr. B. 878 (2010) 3427.
12
[13] P. Hashemi, M. Naderlou, M. Safdarian, A.R. Ghiasvand, Anal. Chem. Lett. 3 (2013) 92.
13
[14] F. Pena-Pereira, I. Lavilla, C. Bendicho, TRAC-Trend. Anal. Chem. 29 (2010) 617.
14
[15] C. Arthur, J. Pawliszyn, Anal. Chem. 62 (1990) 2145.
15
[16] D. Puig, D. Barcelo, TrAC-Trend. Anal. Chem. 15 (1996) 362.
16
[17] Ch. Erger, T. C. Schmidt, TrAC-Trend. Anal. Chem. 61 (2014) 74.
17
[18] M.T. Kelly, M. Larroque, J. Chromatogr. A. 841 (1990) 177.
18
[19] J. Pawliszyn, TrAC-Trends Anal. Chem. 14 (1995) 113.
19
[20] D. Lambropoulou, T. Albanis, J. Biochem. Biophys. Methods. 70 (2007) 195.
20
[21] M.R. Khalili Zanjani, Y. Yamini, S. Shariati, J.A. Jonsson, Anal. Chim. Acta. 585 (2007) 286.
21
[22] P. Viñas, N. Campillo, V. Andruch, TrAC-Trend. Anal. Chem. 68 (2015) 48.
22
[23] F. Kamarei, H. Ebrahimzadeh, Y. Yamini, Microchem. J. 99 (2011) 26.
23
[24] M. Khalili-Zanjani, Y. Yamini, N. Yazdanfar, Sh. Shariati, Anal. Chim. Acta. 606 (2008) 202.
24
[25] Sh. Dadfarni, A. Salmanzadeh, A. Haji Shabani, Anal. Chim. Acta. 623 (2008) 163.
25
[26] D. Afzali; A. Mohadesi, B. Jahromi, M. Falahnejad, Anal. Chim. Acta. 684 (2011) 54.
26
[27] H. Farahani, M. Ganjali, R. Dinarvand, P. Norouzi, Talanta. 76 (2008) 718.
27
[28] A. Tankeviciute, R. Kazlauskas, V. Vickackaite, Analyst. 126 (2001) 1674.
28
[29] M. Ghambarian, M. Khalili-Zanjani, Y. Yamini, A. Esrafili, N. Yazdanfar, Talanta. 81 (2010) 197.
29
[30] Y. Wang, M. Pan, A. Cheng, L. Lin, Ho Y; Hsieh C; Lin J; J. Pharm. Biomed. Anal. 15 (1997) 1867.
30
[31] H. Bagheri, A. Saber, S.R. Mousavi, J Chromatogr. A. 1046 (2004) 27.
31
[32] D.A. Lambropoulou , T.A . Albanis, J. Chromatogr. A. 1049 (2004) 17.
32
[33] N. Gupta, A. Nahata, V. Dixit, Asian. J. Tradit. Med. 5 (2010) 12.
33
ORIGINAL_ARTICLE
Ultra-trace Determination of Palladium(II) by Spectrophotometric Flow Injection Analysis
Nowadays, palladium compounds due to their especial characteristics used in different industries, mainly in electrical power sources and chemical productions as a catalyst. Therefore, Pd concentration is increasing in our around that can be contaminant our environment due its toxic effects. In this work, a simple, selective and rapid flow injection method of analysis (FIA) has been developed for ultra-trace determination of palladium. The method is based on catalytic effect of palladium on the oxidation of naphthol green B by periodate. Naphthol green B undergoes an oxidation reaction with metaperiodate in acidic medium to from a colorless product at very slow rate. It was found that this reaction can be sharply done at the present of trace amount of Pd(II). The reaction was monitored spectrophotometrically by measuring the difference between absorbance of naphthol green B of solutions with and without Pd(II), at the λmax= 721 nm. The reagents and manifold variables, which have influences on the sensitivity, were investigated and the optimum conditions were established. At these conditions, the influences of some important species on the determination of palladium by flow system were examined and most of them do not have any interference effect on its flow injection determination. It is obvious that under the optimized conditions absorbance signal was linearly depended on palladium concentrations in the ranges of 2.0–90.0 ng/mL with a detection limit of 0.9 ng/mL (S/N= 3) and a sample rate of 35±5 samples/h.
https://www.analchemres.org/article_40552_43774ad174ed3a57992f904917d6990d.pdf
2017-06-01
11
20
10.22036/abcr.2017.40552
Palladium(II)
Flow injection analysis
Spectrophotometry
Naphthol green B
Mohsen
Keyvanfard
keyvan45638@yahoo.com
1
Department of Chemistry, Majlesi Branch, Islamic Azad University, Isfahan, 86145-311 Iran
LEAD_AUTHOR
Behzad
Rezaei
rezaeimeister@gmail.com
2
Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111 Iran
AUTHOR
Khadijeh
Alizad
kh.alizad3059@yahoo.com
3
Department of Chemistry, Majlesi Branch, Islamic Azad University, Isfahan, 86145-311 Iran
AUTHOR
[1] S. Daniel, J. Gladis, T. Rao, Anal. Chim. Acta 488 (2003) 173.
1
[2] P. Schramel, M. Zischka, H. Muntauiro, B. Stojanik, R. Dams, M. Gomez Gomez, P. Quevauviller, J. Environ. Monitor. 2 (2000) 443.
2
[3] A. Limbeck, J. Rendl, H. Puxbaum, J. Anal. Atom Spectrom. 18 (2003) 161.
3
[4] D.A. Kezler, J.A. Ibers, Inorg. Chem. 22 (1983) 3366.
4
[5] K.L. Machida, M. Enyo, G.Y. Adachi, J. Shiokawa, B Chem. Soc. Jpn. 60 (1987) 411.
5
[6] A.A. Ensafi, M. Keyvanfard, Spectrochim. Acta A. 58 (2002) 1567.
6
[7] T. Hees, B. Wenclawiak, S. Lustig, P. Schramel, M. Schwarzer, M. Schuster, D. Verstraete, R. Dams, E. Helmers, Environ. Sci. Pollut R 5 (1998) 105. http://www.lenntech.com/periodic/elements/pd.htm
7
[8] S.D. Lee, Ann Arbor Science Publisher. Ann Arbor, MI1980.
8
[9] P. Kovacheva, R. Djingova, Anal. Chim. Acta 464 (2002) 7.
9
[10] M. Schwarzer, M. Schuster, R. von Hentig, Fresen. J. Anal. Chem. 368 (2000) 240.
10
[11] M. Müller, K.G. Heumann, Fresen. J. Anal. Chem. 368 (2000) 109.
11
[12] J. Messerschmidt, A. von Bohlen, F. Alt, R. Klockenkamper, Analyst 125 (2000) 397.
12
[13] E. Najafi, O. Sadeghi, N. Tavassoli, P. Mirahmadpour, H.R. Lotfi Zadeh, Anal. Sci. 26 (2010) 479.
13
[14] S. Mohammadi, D. Afzali, M. Taher, Y. Baghelani, Microchim. Acta 168 (2010) 123.
14
[15] M. Ghaedi, A. Shokrollahi, J. Hazard. Mater. 1022 (2009).
15
[16] T.A. Kokya, K. Farhadi, J. Hazard. Mater. 16 (2009) 726.
16
[17] M. Zeydvandi, N. Pourreza, J. Anal. Chem. 61 (2006) 744.
17
[18] A. Jabbari, M. Barzegar, M. Mohammadi, Indian J. Chem. A 44 (2005) 1215.
18
[19] M.H. Pournaghi-Azar, A. Saadatirad, Electroanal. 22 (2010) 1592.
19
[20] H. Tavallali, M. Jahromi Pisheh Ghanaat, J. Serb. Chem. Soc. 74 (2009) 311.
20
[21] P. Abiman, G.G. Wildgoose, L. Xiao, R.G. Compton, Electroanal. 20 (2008) 1607.
21
[22] M. Taher, A. Mostafavi, S. Mohammadi Mobarakeh, J. Anal. Chem. 62 (2007) 1022.
22
[23] W. Yang, Q. Hu, Z. Huang, J. Yin, G. Xie, J. Serb. Chem. Soc. 71 (2006) 821.
23
[24] F. Yi-wen, D. Xin-fa, X. Liang, W. Wen-jin, L. Wei-ming. Spectrosc. Spect. Anal. 26 (2006) 1912.
24
[25] A.A. Ensafi, M. Chamjangali, H. Rahimi Mansour, Talanta 55 (2001) 715.
25
[26] B. Rezaei, M. Keyvanfard, J. Hazard. Mate. 151 (2008) 456.
26
[27] S. Sacmaci, S. Kartal, Talanta 109 (2013) 26.
27
ORIGINAL_ARTICLE
Polyaniline/Graphene Nanocomposite as a Promising Sorbent for Dispersive Solid Phase Extraction of Avermectins from Citrus Fruit Juice
A solid phase extraction sorbent based on polyaniline/graphene nanocomposite is presented. The structure and morphology of synthesized nanocomposite were investigated by Fourier transform infrared spectroscopy, field emission scanning electron microscopy, X-ray diffraction and thermal gravimetric analysis. The dispersive solid phase extraction was employed to the isolation and preconcentration of avermectins insecticide (mixture of B1a and B1b). The extraction procedure was investigated by high performance liquid chromatography-UV detection. The sorbent demonstrated a favorable analytical performance for avermectins detection with reasonable linear ranges (1.5-1000 μg L-1 and 5.0-1000 μg L-1 for B1a and B1b in order) and acceptable detection limits (0.5 μg L-1 for B1a and 2.5 μg L-1 for B1b) under optimized conditions. The extraction efficiency of polyaniline/graphene nanocomposite in the extraction of avermectins was compared with graphene, polyaniline, carbon nanotube and C18 sorbents. Moreover, the applicability of proposed method was assessed for the extraction of analyte from citrus fruit juice.
https://www.analchemres.org/article_40553_d9bf4df5ddf4ef17f9842957b7a10a43.pdf
2017-06-01
21
29
10.22036/abcr.2017.40553
Polyanilline/graphene nanocomposite
Dispersive solid phase extraction
Avermectins
High performance liquid chromatography
Citrus fruit juice
Faezeh
Khalilian
faezeh.khalilian@yahoo.com
1
Department of Chemistry, College of Basic Science, Yadegar -e- Imam Khomeini (RAH) Shahre Rey Branch, Islamic Azad University, Tehran, Iran
LEAD_AUTHOR
Mohammad
Farajvand
mohamad.farajvand@gmail.com
2
Department of Chemistry, College of Basic Science, Yadegar-e-Imam Khomeini (RAH) Shahre Rey Branch, Islamic Azad University, Tehran, Iran
AUTHOR
[1] Q. Wang, J.A. Chen, Z.M. Liu, S.G. Wu, X.P. Zhao, C.X. Wu, Insect. Sci. 12 (2005( 109.
1
[2] J.L. Shipp, K. Wang, G. Ferguson, Biol. Control 17 (2000) 125.
2
[3] A.I. Valenzuela, D.S. Popa, M.J. Redondo, J. Chromatogr. A 918 (2001) 59.
3
[4] B. Roudant, Analyst 123 (1998) 2541.
4
[5] L. Kolar, J. Kuzjner, N.K. Erzjen, Biomed. Chromatogr. 18 (2004) 117.
5
[6] G.L. Bienvenida, J.F. Garcia-Reyes, M.D. Antonio, Talanta 79 (2009) 109.
6
[7] X. Feas, J.A. Seijas, M.P. Vazquez-Tato, P. Regal, A. Cepeda, C. Fente, Anal.
7
Chim. Acta 631 (2009) 237.
8
[8] F. Khalilian, M. Rezaee, M. Kashani Gorgabi, Anal. Methods 7 (2015) 2182.
9
[9] V. Singh, D. Joung, L. Zhai, S. Das, I. Saiful, S. Seal, Prog. Mater. Sci. 56 (2011) 1178.
10
[10] Q. Liu, J. Shi, G. Jiang, Trends Anal. Chem. 37 (2012) 1.
11
[11] F. Khalilian, S. Ahmadian, J. Sep. Sci. 39 (2016) 1500.
12
[12] N. Li, J. Chen, Y. Shi, Talanta 141 (2015) 212.
13
[13] A. Speltini, M. Sturini, F. Maraschi, L. Consoli, A. Zeffiro, A. Profumo, J. Chromatogr. A 1379 (2015) 9.
14
[14] S. Park, R.S. Ruoff, Nat. Nanotechnol. 4 (2009) 217.
15
[15] M.D. Stoller, S.J. Park, Y.W. Zhu, J.H. An, R.S. Ruoff, Nano Lett. 8 (2008) 3498.
16
[16] K.P. Loh, Q.L. Bao, G. Eda, M. Chhowalla, Nat. Chem. 2 (2010) 1015.
17
[17] P.R. Teasdale, G.G. Wallace, Analyst 118 (1993) 329.
18
[18] S.B. Adeloju, G.G. Wallace, Analyst 121 (1996) 699.
19
[19] A.G. MacDiarmid, Angew. Chem. Int. Ed. 40 (2001) 2581.
20
[20] H. Shirakawa, Angew. Chem. Int. Ed. 40 (2001) 2574.
21
[21] U. Lange, N.V. Roznyatovskaya, V.M. Mirsky, Anal. Chim. Acta 614 (2008) 1.
22
[22] H. Bagheri, N. Alipour, Z. Ayazi, Anal. Chim. Acta 740 (2012) 43.
23
[ 23] H. Bagheri, Z. Ayazib, M. Naderi, Anal. Chim. Acta 767, 12 (2013) 1.
24
[24] L. Liu, H. Liu, Y. Li, X. Wang, X. Du, Anal. Method. 6 (2014) 3467.
25
[25] L. Staudenmaier, Ber. Dtsch. Chem. Ges. 31 (1898) 1481.
26
[26] H. Hu, X. Wang, J. Wang, F. Liu, M. Zhang, C. Xu, Appl. Surf. Sci. 257 (2011) 2637.
27
[27] Y. Li, H. Peng, G. Li, K. Chen, Eur. Polym. J. 48 (2012) 1406.
28
[28] G. Wang, S. Zhuo, W. Xing, Mater. Lett. 69 (2012) 27.
29
[29] G. Wang, W. Xing, S. Zhuo, Electrochim. Acta 66 (2012) 151.
30
[30] W. He, W. Zhang, Y. Li., X. Jing, Synth. Met. 162 (2012) 1107.
31
[31] F. Khalilian, S. Amiri Hanzaki, M. Yousefi, J. Sep. Sci. 38 (2015) 975.
32
[32] K. Pyrzynska, Sep. Purif. Rev. 37 (2008) 372.
33
[33] X. Xie, X. Wang, L. Zhao, Food Anal. Methods 4 (2011) 203.
34
[34] O.J. Pozo, J.M. Marin, J.V. Sancho, F. Hernandez, J. Chromatogr. A 992 (2003) 133.
35
ORIGINAL_ARTICLE
Electrocatalytic Determination of Isoniazid by a Glassy Carbon Electrode Modified with Poly (Eriochrome Black T)
In this work poly eriochrome black T (EBT) was electrochemically synthesized on the glassy carbon electrode as electrode modifier. On the modified electrode, voltammetric behavior of isoniazid (INH) was investigated. The poly (EBT)-modified glassy carbon electrode has excellent electrocatalytic ability for the electrooxidation of isoniazid. This fact was appeared as a reduced overpotential of INH oxidation in a wide operational pH range from 2 to 13. It has been found that the catalytic peak current depends on the concentration of INH and solution pH. The number of electrons involved in the rate determining step was found 1. The diffusion coefficient of isoniazid was also estimated using chronoamperometry technique. The experimental results showed that the mediated oxidation peak current of isoniazid is linearly dependent on the concentration of isoniazid in the ranges of 8.0 × 10-6 – 1.18 × 10-3 M and 2.90 × 10-5 M – 1.67× 10-3 M with differential pulse voltammetry (DPV) and amperometry methods, respectively. The detection limits (S/N = 3) were found to be 6.0 μM and 16.4 μM by DPV and amperometry methods, respectively. This developed method was applied to the determination of isoniazid in tablet samples with satisfactory results.
https://www.analchemres.org/article_40874_a68861fa52cf1889c3cdcf9d5f06cb48.pdf
2017-06-01
31
40
10.22036/abcr.2017.40874
Isoniazid
Poly (eriochrome black T) modified electrode
Voltammetric behavior
Determination
Karim
Asadpour-Zeynali
k.zeynali@gmail.com
1
Department of Analytical Chemistry, Faculty of Chemistry,
University of Tabriz, Tabriz, Iran
LEAD_AUTHOR
Venus
Baghalabadi
v.baghalabadi@yahoo.com
2
Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran
AUTHOR
[1] World Health Organization, Global Tuberculosis Report 2012, 2012, 3.
1
[2] USP DI®, Drug Information for the Health Care Professional, vol. I, 15th ed., (1995) 1627.
2
[3] M.R. Majidi, A. Jouyban, K. Asadpour-Zeynali, Genetic Algorithm Based Potential Selection in Simultaneous Voltammetric Determination of Isoniazid and Hydrazine by Using Partial Least Squares (PLS) and Artificial Neural Networks (ANNs), Electroanal. 17 (2005) 915–918.
3
[4] C.J. Shishoo and M.B. Devani, Nonaqueous titrimetric determination of isoniazid in presence of excess of sodium p-aminosalicylate in dosage forms, J. Pharm. Sci. 59 (1970) 92–93.
4
[5] K.K. Verma, S. Palod, The titrimetric determination of 4-pyridine carboxylic acid hydrazide (isoniazid) in drug formulations with thallium (III), Anal. Lett. 18 (1985) 11–19.
5
[6] A.H.N. Ahmed, S.M.E. Gizawy, H.I.E. Subbagh, Spectrophotometric determination of isoniazid using ethyl 8-quinolyloxyacetate, Anal. Lett. 25 (1992) 73–80.
6
[7] P. Nagaraja, K.C.S. Murthy, H.S. Yathirajan, Spectrophotometric determination of isoniazid with sodium 1,2-naphthoquinone-4-sulphotlate and cetyltrimethyl ammonium bromide, Talanta 43 (1996) 1075–1080.
7
[8] S.A. Benetton, E.R.M. Kedor-Hackmann, M. Santoro, V.M. Borges, Visible spectrophotometric and first-derivative UV spectrophotometric determination of rifampicin and isoniazid in pharmaceutical preparations, Talanta 47 (1998) 639–643.
8
[9] B.G. Gowda, M.B. Melwanki, J. Seetharamappa, K.C.S. Srinivasa Murthy, Spectrophotometric determination of isoniazid in pure pharmaceutical formulations, Anal. Sci. 18 (2002) 839-841.
9
[10] A. Safavi, M.A. Karimi, N.M.R. Hormozi, Sensitive indirect spectrophotometric determination of isoniazid, Spectrochim. Acta Part A 60 (2004) 765–769.
10
[11] Q.M. Li, Z.J. Yang, Spectrophotometric study of isoniazid by using 1,2-naphthoquinone-4-sulfonic acid sodium as the chemical derivative chromogenic reagent, J. Chin. Chem. Soc. 53 (2006) 383–389.
11
[12] H. Zhang, L. Wu, Q. Li, X. Du, Determination of isoniazid among pharmaceutical samples and the patients' saliva samples by using potassium ferricyanide as spectroscopic probe reagent, Anal. Chim. Acta 628 (2008) 67–72.
12
[13] E.F. Oga, Spectrophotometric determination of isoniazid in pure and pharmaceutical formulations using vanillin, Int. J. Pharm. Pharm. Sci. 2 (2010) 55–58.
13
[14] A. Safavi, M.A. Karimi, M.R.H. Nezhad, Flow injection determination of isoniazid using N-bromosuccinimide and N-chlorosuccinimide–luminol chemiluminescence system, J. Pharm. Biomed. Anal. 30 (2003) 1499–1506.
14
[15] Y. Xiong, H.J. Zhou, Z.J. Zhang, D.Y. He, C. He, Flow-injection chemiluminescence sensor for determination of isoniazid in urine sample based on molecularly imprinted polymer, Spectrochim. Acta Part A 66 (2007) 341–346.
15
[16] B. Haghighi, S. Bozorgzadeh, Flow injection chemiluminescence determination of isoniazid using luminol and silver nanoparticles, J. Microchem. 95 (2010) 192–197.
16
[17] P.C. Ioannou, A simple and rapid fluorimetric method for the microdetermination of isonicotinic acid hydrazide, Talanta 34 (1987) 857–860.
17
[18] R.A.S. Lapa, J. Lima, J.L.M. Santos, Fluorimetric determination of isoniazid by oxidation with cerium (IV) in a multicommutated flow system, Anal. Chim. Acta 419 (2000) 17–23.
18
[19] J.O. Svensson, A. Muchtar, and O. Ericsson. Ion-pair high-performance liquid chromatographic determination of isoniazid and acetylisoniazid in plasma and urine. Application for acetylator phenotyping, J. Chromatogr.341 (1985)193–97.
19
[20] H.I. Seifart,W.L. Gent, D.P. Parkin, P.P. van Jaarsveld, P.R. Donald, High-performance liquid chromatographic determination of isoniazid, acetylisoniazid and hydrazine in biological fluids, J. Chromatogr. B 674 (1995) 269–275.
20
[21] E. Calleri, E.D. Lorenzi, S. Furlanetto, Validation of a RP-LC method for the simultaneous determination of isoniazid, pyrazinamide and rifampicin in a pharmaceutical formulation, J. Pharma. Biomed. Anal. 29 (2002) 1089–1096.
21
[22] S. Guermouche, M.H. Guermouche, Solid-phase extraction and HPTLC determination of isoniazid and acetylisoniazid in serum. Comparison with HPLC, J. Chromatogr. Sci. 42 (2004) 250–253.
22
[23] M.Y. Khuhawar, L.A. Zardari, Capillary gas chromatographic determination of isoniazid in pharmaceutical preparations and blood by precolumn derivatization with trifluoroacetylacetone, J. Food Drug Anal. 14 (2006) 323–328.
23
[24] R. Milán-Segovia, G. Pérez-Flores, J.D. Torres-Tirado, X. Hermosillo-Ramírez, M. Vigna-Pérez, S. Romano-Moreno, Simultaneous HPLC determination of isoniazid and acetylisoniazid in plasma, Acta Chromatogr. 19 (2007) 110–118.
24
[25] P.F. Fang, H.L. Cai, H.D. Li, R.H. Zhu, Q.Y. Tan, W. Gao, P. Xu, Y.P. Liu, W.Y. Zhang, Y.C. Chen, F. Zhang, Simultaneous determination of isoniazid, rifampicin, levofloxacin in mouse tissues and plasma by high performance liquid chromatography– tandem mass spectrometry, J. Chromatogr. B 878 (2010) 2286–2291.
25
[26] P. Liu, Z. Fu, J. Jiang, L. Yuan and Z. Lin, Determination of isoniazid concentration in rabbit vertebrae by isotope tracing technique in conjunction with HPLC, Biomed. Chromatogr. 27 (2013) 1150–1156.
26
[27] T.Y. You, L. Niu, J.Y. Gui, S.J. Dong, E.K. Wang, Detection of hydrazine, methylhydrazine and isoniazid by capillary electrophoresis with a 4-pyridyl hydroquinone self-assembled microdisk platinum electrode, J. Pharm. Biomed. Anal. 19 (1999) 231–237.
27
[28] X. Zhang, Y. Xuan, A. Sun, Y. Lv, X. Hou, Simultaneous determination of isoniazid and p-aminosalicylic acid by capillary electrophoresis using chemiluminescence detection, Luminescence 24 (2009) 243–249.
28
[29] M.H. Shah, J.T. Stewart, Amperometric determination of isoniazid in a flowing stream at the glassy carbon electrode, Anal. Lett. 16 (1983) 913–923.
29
[30] M.A.A. Lomillo, O.D. Renedo, M.J.A. Martínez, Resolution of ternary mixtures of rifampicin, isoniazid and pyrazinamide by differential pulse polarography and partial least squares method, Anal. Chim. Acta 449 (2001) 167–177.
30
[31] M.M. Ghoneim, K.Y. El-Baradie, A. Tawfik, Electrochemical behavior of the antituberculosis drug isoniazid and its square-wave adsorptive stripping voltammetric estimation in bulk form, tablets and biological fluids at a mercury electrode, J. Pharm. Biomed. Anal. 33 (2003) 673–685.
31
[32] H.Y. Xia, X.Y. Hu, Determination of isoniazid using a gold electrode by differential pulse voltammetry, Anal. Lett. 38 (2005) 1405–1414.
32
[33] M.R. Majidi, A. Jouyban, K. Asadpour-Zeynali, Voltammetric behavior and determination of isoniazid in pharmaceuticals by using overoxidized polypyrrole glassy carbon modified electrode, J. Electroanal. Chem. 589 (2006) 32–37.
33
[34] G.J. Yang, C.X. Wang, R. Zhang, C.Y. Wang, Q.S. Qu, X.Y. Hu, Poly(amidosulfonic acid) modified glassy carbon electrode for determination of isoniazid in pharmaceuticals, Bioelectrochem. 73 (2008) 37–42.
34
[35] M.F. Bergamini, D.P. Santos, M.V.B. Zanoni, Determination of isoniazid in human urine using screen-printed carbon electrode modified with poly-L-histidine, Bioelectrochemistry 77 (2010) 133–138.
35
[36] K. Asadpour-Zeynali, P. Soheili-Azad, Simultaneous polarographic determination of isoniazid and rifampicin by differential pulse polarography method and support vector regression, Electrochim. Acta 55 (2010) 6570-6576.
36
[37] N.F. Atta, A. Galal, R.A. Ahmed, Voltammetric behavior and determination of isoniazid using PEDOT electrode in presence of surface active agents, Int. J. Electrochem. Sci. 6 (2011) 5097–5113.
37
[38] S. Shahrokhian and M. Amiri, Multi-walled carbon nanotube paste electrode for selective voltammetric detection of isoniazid, Microchim. Acta 157 (2007) 149–158.
38
[39] H. Yao, Y. Sun, X. Lin, Y. Tang, L. Ailin, Li. Guangwen, L. Wei and Z. Shaobo, Selective Determination of Epinephrine in the Presence of Ascorbic Acid and Uric Acid by Electrocatalytic Oxidation at Poly (Eriochrome Black T) Film-Modified Glassy Carbon Electrode, Anal. Sci. 23 (2007) 677–682.
39
[40] H. Yao, Y. Sun, X. Lin, Y. Tang, and L. Haung, Electrochemical Characterization of Poly (Erichrome Black T) Modified Glassy Carbon Electrode and its Application to Simultaneous Determination of Dopamine, Ascorbic Acid and Uric Acid, Electrochim. Acta 52 (2007) 6165–6171.
40
[41] U. Chandra, B.E.K. Swamy, O. Gilbert, S. Reddy, B.Sh. Sherigara, Determination of Dopamine in Presence of Uric Acid at Poly (Eriochrome Black T) Film Modified Graphite Pencil Electrode, American J. Anal. Chem. 2 (2011) 262–269.
41
[42] S. M. Golabi and H. R. Zare, Electroanalysis 11 (1999) 1293–1300.
42
[43] A.J. Bard, L.R. Faulkner, Electrochemical Methods, Fundamentals and Applications, Wiley, New York, 1980, pp 103-104.
43
[44] U. Pratap Azad and Ve. Ganesan, Efficient electrocatalytic oxidation and selective determination of isoniazid by Fe(tmphen)32+-exchanged Nafion®-modified electrode, J. Solid State Electrochem. 16 (2012) 2907–2911.
44
ORIGINAL_ARTICLE
Selective Spectrophotometric Determination of Metformin Hydrochloride in Pharmaceuticals and Urine Using Two Nitrophenols as Chromogenic Agents
Metformin hydrochloride (MFH) is an oral anti-diabetic drug of biguanide class. Two selective spectrophotometric methods were presented for the determination of MFH in pharmaceuticals. The methods were based on the measurement of yellow-coloured charge-transfer complexes formed between MFH and two poly-nitrophenols, namely, 2,4-dinitrophenol (DNP method, at 405 nm) and picric acid (PA method; at 410 nm) in dichloromethane medium. The variables which affect the complex formation were studied and optimized. Beer’s law was obeyed over the concentration ranges: 2.4-48.0 and 3.2-64.0 µg ml-1 with molar absorptivity values of 3.24 × 103 and 2.30 × 103 l mol-1 cm-1, with DNP method and PA method, respectively. The limits of detection (LOD) and quantification (LOQ) were calculated to be 0.13 and 0.40 µg ml-1 for DNP method and 0.19 and 0.59 µg ml-1 for PA method. Methods were validated for accuracy, precision, robustness, ruggedness and selectivity. The proposed methods were applied to the determination of MFH in tablets. The accuracy and precision of the methods were found excellent. Accuracy of the methods was ascertained by recovery test via standard-addition procedure. The methods were applied to spiked human urine sample without detectable interference from endogenous substances.
https://www.analchemres.org/article_40968_9d77813926c58543eac17cd19cd1a5f2.pdf
2017-06-01
41
51
10.22036/abcr.2017.40968
Metformin hydrochloride
Nitrophenols
Spectrophotometry
Charge-transfer complex
Pharmaceuticals
Spiked human urine
Kanakapura
Basavaiah
prasadtnpur@gmail.com
1
Department of Chemistry, University of Mysore, Manasagangothri, Mysuru-570 006, Karnataka, India
LEAD_AUTHOR
N
Rajendraprasad
prasadtnpur@yahoo.co.in
2
PG Department of Chemistry, JSS College of Arts, Commerce & Science, B N Road, Mysuru-570 025, Karnataka, India
AUTHOR
[1] British Pharmacopoeia, Her Majesty’s Stationery Office, London, UK, 2007.
1
[2] C.J. Bailey, M.R.C. Path, R.C. Turner, N. Engl. J. Med. 334 (1996) 574.
2
[3] European Pharmacopoeia, Strasbourg, Council of Europe 6.0 (2007) 2370.
3
[4] The United States Pharmacopoeia, XXXII Revision, the National Formulary XXVII, Rockville, USP Convention 2905 (2009).
4
[5] S. Ashour, R. Kabbani, Anal. Lett. 36 (2003) 361.
5
[6] M.G. El-Bardicy, S.Z. El-Khateeb, A.K.S. Ahmad, H.N. Assad, Spectrosc. Lett. 22 (1989) 1173.
6
[7] S.S.M. Hassan, W.H. Mahmoud, M.A.F. Elmosallamy, O.H.M. Othman, Anal. Chim. Acta 378 (1999) 299.
7
[8] P. Umapathi, J. Ayyappan, S.D. Quine, Trop. J. Pharm. Res. 11 (2012) 107.
8
[9] N.M. Rao, J. Bagyalarshmi, T.K. Ravi, Int. J. Pharm. Sci. Res. 1 (2010) 262.
9
[10] S.Z. El-Khateeb, H.N. Assad, M.G. El-Bardicy, A.S. Ahmad, Anal. Chim. Acta 208 (1988) 321.
10
[11] V.K. Sharma, A. Bhattacharya, Asian J. Chem. 22 (2010) 8273.
11
[12] M.S. Rizk, H.M. Abdel-Fattah, Y.M. Issa, E.M. Atia, Anal. Lett. 26 (1993) 415.
12
[13] A.F. Shoukry, M.S. Rizk, H.M. Abdel-Fattah, Y.M. Issa, E.M. Atia, J. Chem. Technol. Biotechnol. 60 (1994) 217.
13
[14] M.S. Rizk, H.M. Abdel-Fattah, Y.M. Issa, E.M. Atia, J. Chem. Technol. Biotechnol. 61 (1994) 415.
14
[15] M.S. Rizk, Electroanalysis 7 (1995) 687.
15
[16] J.M. Calatayud, M.C.P. Marti, P.C. Falco, Anal. Lett. 18 (1985) 1381.
16
[17] M. Abou-dan, S. Ashour, H. Abou-dan, Asian J. Chem. 13 (2001) 1.
17
[18] F. Al-Rimawi, Talanta 79 (2009) 1368.
18
[19] M. Kar, P. Choudhury, Indian J. Pharm. Sci. 71 (2009) 318.
19
[20] S.I. Bhoir, I.C. Bhoir, M. Sundaresan, Indian J. Pharm. Sci. 65 (2003) 650.
20
[21] A.E. Gindy, M.W. Nassar, N.M.E. Abasawy, K.A.S. Attia, M.A. Shabrawi, J. AOAC Int. 93 (2010) 1821.
21
[22] K. Devendra, S. Saurabh, R. Rachumallu, K.D. Rakesh, World J. Pharm. Pharm. Sci. 3 (2014) 745.
22
[23] P. Gomes, J. Sippel, A. Jablonski, M. Steppe, J. Pharm. Biomed. Anal. 36 (2004) 909.
23
[24] J. Radhakrishna, J. Satyanarayana, A. Satyanarayana, J. Pharm. Biomed. Anal. 29 (2002) 873.
24
[25] M. Vasudevan, J. Ravi, S. Ravisankar, B. Suresh, J. Pharm. Biomed. Anal. 25 (2001) 77.
25
[26] D.H. Khanolkar, V.M. Shindhe, Indian Drugs 36 (1999) 739.
26
[27] M.S. Arayne, N. Sultana, M.H. Zuberi, Pakistan J. Pham. Sci. 19 (2006) 231.
27
[28] R.T. Sane, V.J. Banavalikar, V.R. Bhate, V.G. Nayak, Indian Drugs 26 (1989) 647.
28
[29] I.I. Handom, A.K.J. Bani, A.M. Abushoffa, J. Pharm. Biomed. Anal. 53 (2010) 1254.
29
[30] G. Mubben, K. Noor, Indian J. Pharm. Sci. 71 (2009) 100.
30
[31] P.P. Vandana, J.D. Subhash, H.K. Suvarna, T.K. Sudarshan, O.K. Pramod, J. Indian Chem. Soc. 91 (2014) 171.
31
[32] P. Pignard, Ann. Biol. Clin. 20 (1962) 325.
32
[33] G. Siest, F. Ross, J.J. Gabou, Bull. Soc. Pharm. 58 (1963) 29.
33
[34] E.R. Garret. J. Tsau, J. Pharm. Sci. 16 (1972) 1404.
34
[35] A. Bhal, B.S. Bhal, Text Book of Advanced Organic Chemistry, 1st ed., 1977, p. 1069.
35
[36] N. Singh, A. Ahmad, Canadian J. Anal. Sci. Spectrum. 54 (2009) 292.
36
[37] G. Saito, Y. Matsungo, Bull. Chem. Soc. Japan 44 (1971) 3328.
37
[38] Y. Matsungo, G. Saito, Bull. Chem. Soc. Japan 45 (1972) 1972.
38
[39] G. Saito, Y. Matsungo, Bull. Chem. Soc. Japan 46 (1973) 714.
39
[40] R.S. Mulliken, J. American Chem. Soc. 72 (1950) 600.
40
[41] R.S. Mulliken, J. American Chem. Soc. 74 (1952) 811.
41
[42] K.N. Prashanth, K. Basavaiah, Chem. Sci. J. 3 (2012) 1, Article ID CSJ-71.
42
[43] M.S. Raghu, K. Basavaiah, J. Assoc. Arab Univ. Basic Appl. Sci. 12 (2012) 33.
43
[44] C.S. Xuan, Z.Y. Wang, J.L. Sing, Anal. Lett. 31 (1998) 1185.
44
[45] W.F. El-Hawary, N.M. Issa, A. Talat, Int. J. Biomed. Sci. 3 (2007) 50.
45
[46] S. Sadeghi, M. Shamshipur, Anal. Lett. 31 (1998) 2691.
46
[47] E. Regulska, M. Terasiewiez, H. Prizanonska-Tarasiewiez, J. Pharm. Biomed. Anal. 27 (2002) 335.
47
[48] F.A. El-Yazbi, A.A. Gazy, H.M. Mahgoub, M.A. El-Sayed, R.M. Youssef, J. Pharm. Biomed. Anal. 31 (2003) 1027.
48
[49] M.E. Mahrous, Anal. Lett. 25 (1992) 269.
49
[50] Y.M. Issa, A.S. Amin, Anal. Lett. 26 (1993) 2397.
50
[51] W. Kemp, Organic Spectroscopy, 3rd ed., Replika Press, India, 2006, p. 274.
51
[52] A.S. Douglas, M.W. Donald, Principles of Instrumental Analysis, New York, Holt, Renehart, Winston, str., 1971, p. 104.
52
[53] International Conference on Harmonization of Technical Requirements for Registration of Pharmaceuticals for Human Use, ICH Harmonized Tripartite Guideline, Validation of Analytical Procedures: Text and Methodology Q2(R1), Complementary Guideline on Methodology, London, 2005.
53
[54] ICH Harmonised Tripartite Guideline prepared within the Third International Conference on Harmonisation of Technical Requirements for the Registration of Pharmaceuticals for Human Use (ICH), Text on Validation of Analytical Procedures, 1994.
54
ORIGINAL_ARTICLE
Photocatalytic Degradation of Anionic Azo Dyes Acid Orange 7 and Acid Red 88 in Aqueous Solutions Using TiO2-containing Hydrogel
The photocatalytic degradation of two anionic azo dyes Acid Red88 (AR 88) and Acid Orange 7 (AO7) was investigated in aqueous solution using a TiO2-containing hydrogel and UV light. The pH-sensitive hydrogel poly (styrene-alt-maleic anhydride) (PSMA), was synthesized and crosslinked in the presence of melamine and TiO2 nanoparticles which results in entrapment of TiO2 into the melamine-grafted PSMA (M-g-PSMA) hydrogel. Potential application of this nanocomposite for removal of azo dyes from wastewater was studied and the effective parameters on degradation process including time, initial pH value of the solutions, temperature and amount of added nanocomposite were optimized. The optimized values for effective parameters are as follows: time: 30 min, initial pH of the solutions: 5.23 for AO7 and 5.3 for AR88, temperature: 24 ºC and amount of added nanocomposite: 250 mg. Results showed that in optimum experimental conditions the removal percentages are about %94 for AR88 and %71 for AO7 indicating good removal performance toward the method whilst pH-sensitivity of the nanocomposite facilitates retrieval of nanocatalyst at the end of the reaction.
https://www.analchemres.org/article_41098_254fa8b88fe3151eef0e770efe24f8e9.pdf
2017-06-01
53
63
10.22036/abcr.2017.41098
Photocatalytic degradation
Hydrogel
TiO2
Azo dye
Acid Red 88
Acid Orange 7
Morteza
Bahram
m.bahram@urmia.ac.ir
1
Department of Chemistry, Faculty of Science, Urmia University, Urmia, Iran
LEAD_AUTHOR
Saed
Salami
saedchemistry007@gmail.com
2
Department of Chemistry, Faculty of Science, Urmia University, Urmia, Iran
AUTHOR
Mehdi
Moghtader
mehdimahz2@gmail.com
3
Department of Chemistry, Faculty of Science, Urmia University, Urmia, Iran
AUTHOR
Peyman
Najafi Moghadam
p_najafi27@yahoo.com
4
Department of Chemistry, Faculty of Science, Urmia University, Urmia, Iran
AUTHOR
Amir
Reza Fareghi
amir_fareghi@yahoo.com
5
Department of Chemistry, Faculty of Science, Urmia University, Urmia, Iran
AUTHOR
Masoumeh
Rasoli
m376ar@yahoo.com
6
Department of Science, Payame Noor University, Urmia Branch, Urmia, Iran
AUTHOR
Samaneh
Salimpoor
sm.salimpoor@yahoo.com
7
Department of Science, Payame Noor University, Urmia Branch, Urmia, Iran
AUTHOR
[1] P.S. Harikumar, J. Litty, A. Dhanya, J. Environ. Eng. Ecol. Sci. 2 (2013) 1.
1
[2] E. Akceylan1, S. Erdemir, J. Incl. Phenom. Macrocycl. Chem. 82 (2015) 471.
2
[3] H.J. Mansoorian, E. Bazrafshan, A. Yari, M. Alizadeh, Health Scope. 3 (2014) e15507.
3
[4] M. Lučić, N. Milosavljević, M. Radetić, Z. Šaponjić, M. Radoičić, M. K. Krušic. Sep. Purif. Technol. 122 (2014) 206.
4
[5] F. Feng, Z. Xu, X. Li, W. You, Y. Zhen, J. Environ. Sci. 22 (2010) 1657.
5
[6] Z. He, L. Lin, S. Song, M. Xia, L. Xu, H. Ying, J. Chen, Sep. Purif. Technol. 62 (2008) 376.
6
[7] M. Bahram, R. Talebi, A. Naseri, S. Nouri, Chiang Mai J. Sci. 41 (2014) 1230.
7
[8] B.M. Kalejahi, M. Bahram, A. Naseri, S. Bahari, M. Hasani, J. Iran. Chem. Soc. 11 (2014) 241.
8
[9] A. Naseri, R. Barati, F. Rasoulzadeh, M. Bahram, Iran. J. Chem. Chem. Eng. 34 (2015) 51.
9
[10] M. Bahram, S. Asadi, G. Karimnezhad, J. Iran. Chem. Soc. 13 (2015) 639.
10
[11] M. Bahram, M. Hasani. S. Bahari, J. Iran. Chem. Soc. 13 (2016) 449.
11
[12] M. Azami, M. Bahram, S. Nouri, Curr. Chem. Lett. 2 (2013) 57.
12
[13] M. Azami, M. Bahram, S. Nouri, A. Naseri, J. Serb. Chem. Soc. 77 (2012) 235,
13
[14] V.K. Gupta, A. Mittal, V. Gajbe, J. Mittal, Ind. Eng. Chem. Res. 45 (2006) 1446.
14
[15] S.T. Akar, T. Alp, D. Yilmazer, J. Chem. Technol. Biot. 88 (2013) 293.
15
[16] A. Fernandes, A. Morão, M. Magrinho, A. Lopes, I. Gonçalves, Dyes. Pigments. 61 (2004) 287.
16
[17] G. Li, J. Qu, X. Zhang, J. Ge, Water. Res. 40 (2006) 213.
17
[18] A. Özcan, M.A. Oturan, N. Oturan, Y. Şahin, J. Hazard. Mater. 163 (2009) 1213.
18
[19] A. Ozcan, M. Gençten, Chemosphere 146 (2016) 245.
19
[20] P. Ji, J. Zhang, F. Chen, M. Anpo, Appl. Catal. 85 (2009) 148.
20
[21] G. Li, K.H. Wong, X. Zhang, C. Hu, J. C. Yu, R.C.Y. Chan, P.K. Wong, Chemosphere 76 (2009) 1185.
21
[22] R. Yuan, S.N. Ramjaun, Z. Wang, J. Liu, J. Hazard. Mater. 196 (2011) 173.
22
[23] P. Muthirulann, C.N. Devi, M.M. Sundaram, Ceram. Int. 40 (2014) 5945.
23
[24] S. Hu, F. Zhou, L. Wang, J. Zhang, Catal. Commun. 12 (2011) 794.
24
[25] M.E. Olya, A. Pirkarami, M. Soleimani, M. Bahmaei, J. Environ. Manage. 121 (2013) 210.
25
[26] K. Balachandran, R. Venckatesh, R. Sivaraj, P. Rajiv, Spectrochim. Acta A. 128 (2014) 468.
26
[27] P. Sathishkumar, S. Anandan, P. Maruthamuthu, T. Swaminathan, M. Zhou, M. Ashokkumar, Colloids. Surf. A. 375 (2011) 231.
27
[28] P. Sathishkumar, R. Sweena, J.J. Wu, S. Anandan, Chem. Eng. J. 171 (2011) 136.
28
[29] C.C. Carias, J.M. Novais, S. Martins-Dias, Bioresour. Technol. 99 (2008) 243.
29
[30] M.D. Chengalroyen, E.R. Dabbs, World. J. Microbiol. Biotechnol. 29 (2013) 389.
30
[31] R.G. Saratale, G.D. Saratale, J.S. Chang, S.P. Govindwar, J. Taiwan. Inst. Chem. E. 42 (2011) 138.
31
[32] M.A. Rauf, S.S. Ashraf, Chem. Eng. J. 151 (2009) 10.
32
[33] C. Xu, L. Cao, G. Su, W. Liu, H. Liu, Y. Yu, X. Qu, J. Hazard. Mater. 176 (2010) 807.
33
[34] K. Vinodgopal, P.V. Kamat, Environ. Sci. Techno. 29 (1995) 841.
34
[35] K. Vinodgopal, I. Bedja, P.V. Kamat, Chem. Mater. 8 (1996) 2180.
35
[36] T. Wang, H. Wang, P. Xu, X. Zhao, Y. Liu, S. Chao, Thin Solid Films 334 (1998) 103.
36
[37] M.A. Behnajady, N. Modirshahla, R. Hamzavi, J. Hazard. Mater. 133 (2006) 226.
37
[38] C. Tian, Q. Zhang, A. Wu, M. Jiang, Z. Liang, B. Jiang, H. Fu, Chem. Commun. 48 (2012) 2858.
38
[39] A. Ajmal, I. Majeed, R.N. Malik, H. Idriss, M.A. Nadeem, RSC Adv. 4 (2014) 37003.
39
[40] I.K. Konstantinou, T.A. Albanis, Appl. Catal. B-Environ. 49 (2004) 1.
40
[41] M. Nikazar, K. Gholivand, K. Mahanpoor, Desalination 219 (2008) 293.
41
[42] S.X. Liu, X.Y. Chen, X. Chen, J. Hazard. Mater. 143 (2007) 257.
42
[43] Z. Sun, C. Bai, S. Zheng, X. Yang, R.L. Frost, Appl. Catal. A-Gen. 458 (2013) 103.
43
[44] Y. Luo, J. Liu, X. Xia, X. Li, T. Fang, S. Li, Q. Ren, J. Li, Z. Jia, Mater. Lett. 61 (2007) 2467.
44
[45] L. Marija, M. Nedeljko, R. Maja, Š. Zoran. R. Marija, K.K. Melina, Polym. Composite. 35 (2014) 806.
45
[46] J.S. Im, B.C. Bai, S.J. In, Y.S. Lee, J. Colloid. Interf. Sci. 346 (2010) 216.
46
[47] W. Kangwansupamonkon, W. Jitbunpot, S. Kiatkamjornwong, Polym. Degrad. Stabil. 95 (2010) 1894.
47
[48] S.M. Henry, M.E.H. El-Sayed, C.M. Pirie, A.S. Hoffman, P.S. Stayton, Biomacromolecules 7 (2006) 2407.
48
[49] J. Ryu, W.Choi, Environ. Sci. Technol. 42 (2008) 294.
49
[50] S. Shafaghi, P. Najafi Moghadam, A.R. Fareghi, M. M. Baradarani, J. Appl. Polym. Sci. 131 (2014) 40389.
50
[51] M.L. Škorić, I. Terzić, N. Milosavljević, M. Radetić,
51
Z. Šaponjić, M. Radoičić, M.K. Krušić, Eur. Polym. J., 82 (2016) 57.
52
ORIGINAL_ARTICLE
Removal of Alizarin Red and Purpurin from Aqueous Solutions Using Fe3O4 Magnetic Nanoparticles
The applicability of Fe3O4 nanoparticles (Fe3O4NPs) for removing alizarin and purpurin from aqueous solutions has been reported. The influence of nanoparticle dosage, pH of the sample solution, individual dye concentration, contact time between the sample and the adsorbent, temperature, and ionic strength of the sample solution were studied by performing a batch adsorption technique. The maximum removal of 5-100 mg l-1 of individual dyes from an aqueous sample solution at pH 5.0 was achieved within 5.0 min when an adsorbent amount of 20 mg was used. The kinetic results revealed that the pseudo-second-order equation is the best model to analyze the adsorption mechanism. The isotherm analysis indicated that the equilibrium data are well fitted to the Langmuir isotherm model with maximum adsorption capacities of 45.87 and 40.48 mg g-1 of the adsorbent for removal of alizarin and purpurin, respectively. According to the experimental results, about 99% of alizarin and 95% of purpurin were removed from aqueous solutions under applying the optimal experimental conditions.
https://www.analchemres.org/article_41099_19b94dad40d0ad20f40d93b11a888680.pdf
2017-06-01
65
77
10.22036/abcr.2017.41099
Iron oxide magnetic nanoparticles
Alizarin red
Purpurin
Dye removal
Anthraquinone dyes
Ghodratollah
Absalan
gubsulun@yahoo.com
1
Professor Massoumi Laboratory, Department of Chemistry, Faculty of Sciences, Shiraz University, Shiraz 71454, Iran
AUTHOR
Asma
Bananejad
bananezhad@yahoo.com
2
Professor Massoumi Laboratory, Department of Chemistry, Faculty of Sciences, Shiraz University, Shiraz 71454, Iran
AUTHOR
Maryam
Ghaemi
mghaemi@inio.ac.ir
3
Department of Marine Science, Iranian National Institute for Oceanography and Atmospheric Science, No. 3, Etemadzadeh St., Fatemi Ave., Tehran, 1411813389, IR Iran
LEAD_AUTHOR
[1] Y. Anjaneyulu, N. Sreedhara Chary, D. Samuel Suman, Environ. Sci. Technol. 4 (2005) 245.
1
[2] G. Sreelatha, P. Padmaja, J. Envir. Protect. Sci. 2 (2008) 63.
2
[3] D. Bilba, D. Suteu, T. Malutan, Cent. Eur. J. Chem. 6 (2008) 258.
3
[4] J.H. Weisburger, Mutat. Res. 506 (2002) 9.
4
[5] H. Schweppe, J. Winter, Madder and Alizarin, Artists Pigments, in: E. West Fitzhugh (Ed.), OxfordUniversity Press, Oxford, 1997.
5
[6] M. Panizza, M.A. Oturan, Electrochim. Acta 56 (2011) 7084.
6
[7] C. Galindo, P. Jacques, A. Kalt, Chemosphere 45 (2001) 997.
7
[8] C. Saez, M. Panizza, M.A. Rodrigo, G. Cerisola, J. Chem. Technol. Biotechnol. 82 (2007) 575.
8
[9] A.M. Faouzi, B. Nasr, G. Abdellatif, Dyes Pigm. 73 (2007) 86.
9
[10] F. Yi, S. Chen, J. Por. Mater. 15 (2008) 565.
10
[11] M. Panizza, G. Cerisola, Water Res. 43 (2009) 339.
11
[12] L. Fan, Y. Zhang, X. Li, Ch. Luo, F. Lu, H. Qiu, Colloids Surf. B 91(2012) 250.
12
[13] M. Dabiri, Sh. Salimi, A. Ghassempour, A. Rassouli, M. Talebi, J. Sep. Sci. 28 (2005) 387.
13
[14] V.K. Gupta, S. Khamparia; I. Tyagi, D. Jaspal, A. Malviya, A review, Global J. Environ. Sci. Manage. 1 (2015) 71.
14
[15] D. Shao, G. Hou, J. Li, T. Wen, X. Ren, X. Wang, Chem. Eng. J. 255 (2014) 604.
15
[16] Y. Huang, J. Li, X. Chen, X. Wang, R. Soc. Chem. Adv. 4 (2014) 62160.
16
[17] S. Zhang, M. Zeng, W. Xu, J. Li, J. Li, J. Xu, X. Wang, Dalton Trans. 42 (2013) 7854.
17
[18] M. Faraji, Y. Yamini, M. Rezaee, J. Iran. Chem. Soc. 7 (2010) 1.
18
[19] G. Absalan, M. Asadi, S. Kamran, L. Sheikhian, D. M. Goltz, J. Hazard. Mater. 192 (2011) 476.
19
[20] R. Manohar, V.S. Shrivastava, J. Mater. Environ. Sci. 6 (2015) 11.
20
[21] W. Song, M. Liu, R. Hu, X. Tan, J. Li, Chem. Eng. J. 246 (2014) 268.
21
[22] B. Saha, S. Das, J. Saikia, G. Das, J. Phys. Chem. C 115 (2011) 8024.
22
[23] M. Safarikov, I. Safarik, Eur. Cell. Mater. 3 (2002) 192.
23
[24] M. Ghaemi, G. Absalan, J. Iran. Chem. Soc. 12 (2015) 1.
24
[25] M. Ghaemi, G. Absalan, L. Sheikhian, J. Iran. Chem. Soc. 11 (2014) 1759.
25
[26] M.V. Canamares, J.V. Garcia-Ramos, C. Domingo, S. Sanchez-Cortes, J. Raman Spectrosc. 35 (2004) 921.
26
[27] V.P. Glazunov, A.Y. Tchizhova, N.D. Pokhilo, V.Ph. Anufriev, G.B. Elyakov, Tetrahedron 58 (2002) 1751.
27
[28] B. Zargar, H. Parham, A. Hatamie, Talanta 77 (2009) 1328.
28
[29] S. Pirillo, Marı´a Luja´n Ferreira, H. Elsa, Ind.Eng. Chem. Res. 46 (2007) 8255.
29
[30] S. Pirillo, Marı´a Luja´n Ferreira, H. Elsa, J. Hazard. Mater. 168 (2009) 168.
30
[31] M.N. Bakola-Christianopoulou, Polyhedron 3 (1984) 729.
31
[32] L.J. Larson, J.I. Zink, Inorg. Chim. Acta 169 (1990) 71.
32
[33] S. Yariv, S. Shoval, J. Chem. 22 (1982) 259.
33
[34] D.J. Greenland, Soil Fert. 28 (1965) 415.
34
[35] M. Alkan, M. Dogan, J. Colloid Interface Sci. 243 (2001) 280.
35
[36] I. Langmuir, J. Am. Chem. Soc. 40 (1918) 136.
36
[37] H.M.F. Freundlich, J. Phys. Chem. 57 (1906) 385.
37
[38] S. Lagergren, K. Svenska, Vetensk.- Akad. Handl. 24 (1898) 1.
38
[39] Y.S. Ho, G. Mckay, Chem. Eng. J. 70 (1998) 115.
39
[40] L. Ford, Ch. M. Rayner, R.S. Blackburn, Phytochemistry 117 (2015) 168.
40
[41] M. Gholivand, Y. Yamini, M. Dayeni, Sh. Seidi, E. Tahmasebi, J. Environ. Chem. Eng. 3 (2015) 529.
41
[42] M. Roosta, M. Ghaedi, M. Mohammadi, Powder Technol. 267 (2014) 134.
42
[43] M. Fayazi, M. Ghanei-Motlagh, M.A. Taher, Mater. Sci. Semicond. Process. 40 (2015) 35.
43
ORIGINAL_ARTICLE
Immunoassay for Human Chorionic Gonadotropin Based on Glassy Carbon Electrode Modified with an Epitaxial Nanocomposite
A highly sensitive electrochemicalimmunosensor was developed to detect hCG based on immobilization ofhCG-antibody (anti-hCG) onto robust nanocomposite containing Gr, Chit,1-methyl-3-octyl imidazolium tetra fluoro borate ionic liquid (IL)(Gr-IL-Chit). AuNPs were used to immobilize hCG antibody on the modifiedelectrode. The amine groups of the antibody are covalently attached toAuNPs/Gr-IL-Chit nanocomposite. CV, EIS and SEM were employed to characterizethe assembly process and the performance of the immunosensor. DPV and EISstudies demonstrated that the formation of antibody-antigen complexes decreasedpeak current and increased Rct of [Fe(CN)6]3−/4−redox pair at the AuNPs/Gr-IL-Chit/GCE. The optimization of the pH ofsupporting electrolyte and the incubation time were studied in details. Becauseof the synergistic effect of IL, Chit and Gr and the unique properties ofAuNPs, the obtained immunosensor exhibited a wide linear response to hCG in tworanges from 0.005-1.484 and 1.484-411.28 (mIU ml-1). A relativelylow detection limit of 0.0016 mIU ml-1 (S/N = 3) was calculated fromDPV. Satisfactory results were obtained for determination of hCG in human serumsamples.
https://www.analchemres.org/article_41612_f6a42c09754fa8926931be53e3e2db3c.pdf
2017-06-01
79
90
10.22036/abcr.2016.55142.1099
Electrochemical immunosensor
Human chorionic gonadotropin
Nanocomposite
Impedance spectroscopy
Akram
Valipour
akramvalipoor229@gmail.com
1
Department of Chemistry, Ilam University, Ilam, Iran
AUTHOR
Mahmoud
Roushani
mahmoudroushani@yahoo.com
2
Department of Chemistry, University of Ilam, Ilam, Iran
LEAD_AUTHOR
[1] T. Fang, Y. Feng, J. Huangxian, Biosens. Bioelectron. 22 (2007) 2945.
1
[2] F.J. Morgan, Endocrinology 88 (1971) 1045.
2
[3] O.M. Bahl, R.B. Carlsen, R. Bellisario, N. Swaminathan, Biochem. Biophys. Res. Commun. 48 (1972) 416.
3
[4] H. Lund, S.B. Torsetnes, E. Paus, K. Nustad, L. Reubsaet, T.G. Halvorsen, J. Protein. Res. 8 (2009) 5241.
4
[5] J. Wang, R. Yuan, Y. Chai, S. Cao, S. Guan, P. Fu, Li. Min, Biochem. Eng. J. 51 (2010) 95.
5
[6] Q. Wei, R. Li, B. Du, D. Wu, Y. Han, Y. Cai, Y. Zhao, X. Xin, H. Li, M. Yang, Sens. Actuators, B 153 (2011) 256.
6
[7] J.Y. Sun, K.J. Huang, S.F. Zhao, Y. Fan, Z.W. Wu, Bioelectrochemistry 82 (2011) 125.
7
[8] K.J. Huang, D.J. Niu, W.Z. Xie, W. Wang, Anal. Chim. Acta 659 (2010) 102.
8
[9] G. Frens, Nature Phys. Sci. 241 (1973) 20.
9
[10] W.S. Sutherland, J.D. Winefordner, J. Colloid Interface Sci. 148 (1992) 129.
10
[11] R. Chai, R. Yuan, Y.Q. Chai, C.F. Ou, S.R. Cao, X.L. Li, Talanta 74 (2008) 1330.
11
[12] G.M. Yang, Y.B. Chang, H. Yang, L. Tan, Z.S. Wu, X.X. Lu, Y.H. Yang, Anal. Chim. Acta 644 (2009) 72.
12
[13] M. Tao, X.F. Li, Z.S. Wu, M Wang, H. Mei, Y.H. Yang, Clin. Chim. Acta 412 (2011) 550.
13
[14] G.M. Yang, X.Y. Yang, C.Y. Yang, Y.H. Yang, Colloids Surf. A: Physico Chem. Eng. Asp, 389 (2011) 195.
14
[15] Q. Wei, R. Li, B. Du, D. Wu, Y. Han, Y. Cai, Y. Zhao, X. Xin, H. Li, M. Yang, Sens. Actuators, B 153 (2011) 256.
15
[16] R. Li, D. Wu, H. Li, C. Xu, H. Wang, Y. Zhao, Y. Cai, Q. Wei, B. Du, Anal. Biochem. 414 (2011) 196.
16
[17] D. Wu, Y. Zhang, L. Shi, Y. Cai, H. Ma, B. Du, Q. Wei, Electroanalysis 25 (2013) 427.
17
[18] L. Yang, H. Zhao, Sh. Fan, Sh. Deng, Q. Lv, J. Lin, C.P. Li, Biosens. Bioelectron. 57 (2014) 1996.
18
ORIGINAL_ARTICLE
Spectrophotometric Multicomponent Analysis of Ternary and Quaternary Drug Mixtures in Human Urine Samples by Analyzing First-order Data
A new method was developed for the spectral resolution by further determination of three- and four-component mixtures of drugs in urine samples through the complementary application of multivariate curve resolution-alternating least squares with correlation constraint. In the current study, a simple method was proposed to construct a calibration set for the mixture of drugs in the presence of all possible interferents in the human urine samples collected, in duplicate, from volunteers. First, urine samples were collected without any dosage of drugs. Then, urine samples containing a specific brand of drugs were collected. The collected urine samples without any dosage of drugs were spiked with a different concentration of analytes to construct a calibration set; therefore, the proposed method might be successfully used in the presence of matrix effects and unknown calibrated interferences in human urine using first-order data. In this method, a smaller number of calibration samples were used as compared to first-order multivariate calibration methods. Despite intense spectral overlapping and the presence of interferents in the test samples, the results indicated good analytical performance towards the analytes. By calibrating all present components in the unknown samples and imposing the known values in calibration samples during iterations as a correlation constraint, accurate concentrations of the analytes in the unknown set could be predicted. The maximum and minimum band boundaries of feasible solutions corresponding to the species profiles were estimated. The proposed method was used to determine ternary and quaternary mixtures of drugs in urine samples.
https://www.analchemres.org/article_41613_8c2259a38b013145e482823f40eb2e66.pdf
2017-06-01
91
103
10.22036/abcr.2016.60174.1116
MCR-ALS
Ternary mixture of drugs
Quaternary mixture of drugs
First order data
Human urine
Abdolhossein
Naseri
ab.naseri@gmail.com
1
Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz 51644-14766, Iran
LEAD_AUTHOR
Bahar
Ghasemzadeh
bahar_ghasemzadeh@yahoo.com
2
Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz 51644-14766, Iran
AUTHOR
Saheleh
Sheykhizadeh
sheikhizadehsaheleh@yahoo.com
3
Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz 51644-14766, Iran
AUTHOR
[1] N. Mohseni, M. Bahram, A.C. Olivieri, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 122 (2014) 721.
1
[2] H.C. Goicoechea, A.C. Olivieri, R. Tauler, Analyst 135 (2010) 636.
2
[3] W. Van der Linden, Pure Appl. Chem. 61 (1989) 91.
3
[4] K.S. Booksh, B.R. Kowalski, Anal. Chem. 66 (1994) 782A.
4
[5] R. Bro, Anal. Chim. Acta 500 (2003) 185.
5
[6] A. Naseri, M. Bahram, M. Mabhooti, J. Brazilian Chem. Soc. 22 (2011) 2206.
6
[7] A. De Juan, E. Casassas, R. Tauler, 2002, Wiley: Chichester, UK.
7
[8] B.M. Kalejahi, M. Bahram, A. Naseri, S. Bahari, M. Hasani, J. Iran. Chem. Soc. 11 (2014) 241.
8
[9] A. Naseri, H. Abdollahi, Anal. Methods 3 (2011) 429.
9
[10] E. Spjøtvoll, H. Martens, R. Volden, Technometrics 24 (1982) 173.
10
[11] R. Tauler, A. Smilde, B. Kowalski, J. Chemometrics 9 (1995) 31.
11
[12] M. Antunes, J.J. Simão, A. Duarte, R. Tauler, Analyst 127 (2002) 809.
12
[13] M.B. Mamián-López, R.J. Poppi, Anal. Bioanal. Chem. 405 (2013) 7671.
13
[14] T.R. Azzouz, Tauler, Talanta 74 (2008) 1201.
14
[15] M.B.mMamián-López, R.J. Poppi, Anal. Chim. Acta 760 (2013) 53.
15
[16] G. Ahmadi, R. Tauler, H. Abdollahi, Chemomet. Intell. Lab. Systems 142 (2015) 143.
16
[17] C. Theivarasu, S. Ghosh, T. Indumathi, Asian J. Pharmaceutical Clinical Res. 3 (2010) 64.
17
M.C. Ferraro, P.M. Castellano, T.S. Kaufman, J. Pharmaceut. Biomed. Anal. 34 (2004) 305.
18
[18] A. Golcu, M. Dolaz, S. Serin, Turkish J. Chem. 25 (2001) 485.
19
[19] M.K. Angier, R.J. Lewis, A.K. Chaturvedi, D.V. Canfield, J. Anal. Toxicol. 29 (2005) 517.
20
[20] L. Clohs, K.M. McErlane, J. Pharmaceut. Biomed. Anal. 31 (2003) 407.
21
[21] M. Behpour, E. Honarmand, S. Ghoreishi, Bulletin of the Korean Chem. Soc. 31 (2010) 845.
22
[22] L. Benet, S. Øie, J. Schwartz, 1996, New York: McGraw Hill Book Company.
23
[23] B. Pharmacopoeia, London, UK, 2005, pp. 29-69.
24
[24] E.D. Medicines, Suppl. General, (2002). p. 25.
25
[25] R. Hajian, N. Afshari, J. Chem. 9 (2012) 1153.
26
[26] M. Khanmohammadi, M. Soleimani, F. Morovvat, A.B. Garmarudi, M. Khalafbeigi, K. Ghasemi, Thermochimica Acta 530 (2012) 128.
27
[27] M. Qi, P. Wang, Y. Lang, J. Lang, R. Fu, J. Chromatogr. Sci. 40 (2002) 45.
28
[28] M. Fathinia, A. Khataee, A. Naseri, S. Aber, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 136, Part C, 2015, pp. 1275-1290.
29
[29] A. Naseri, S. Hosseini, F. Rasoulzadeh, M.-R. Rashidi, M. Zakery, T. Khayamian, J. Luminescence 157 (2015) 104.
30
[30] J. Jaumot, A. de Juan, R. Tauler, Chemomet. Intell. Lab. Systems 140 (2015) 1.
31
[31] J. Parojčić, K. Karljiković-Rajić, Z. Durić, M. Jovanović, S. Ibrić, Biopharm. Drug Dispos. 24 (2003) 309.
32
[32] A. de Juan, R. Tauler, Anal. Chim. Acta 500 (2003) 195.
33
[33] R. Bro, S. De Jong, J. Chemometrics 11 (1997) 393.
34
[34] L.B. Lyndgaard, F. van den Berg, A. de Juan, Chemomet. Intell. Lab. Systems 125 (2013) 58.
35
[35] C.I. Beyer, Alting, E. Backer, Clinical Chem. 39 (1993) 1743.
36
ORIGINAL_ARTICLE
Ultrasonic and Cooling Approaches for Reinforcement of the Microextraction Methods
Since solid-phase and liquid-phase microextraction (SPME and LPME) were introduced, as effective solvent-free methods, many efforts have been made to improve their modes and applications. However, due to limitations with sensitivity and efficiency, researchers have focused on improving the performance of their basic primary modes. In this way, in recent years, different methods such as ultrasonic-assisted microextraction (UA-ME), microwave-assisted microextraction (MA-ME), solvent-assisted microextraction (SA-ME) and cooling-assisted microextraction (CA-ME) were developed to reinforce the efficiency of the SPME and LPME methods. These strategies make the microextraction methods more effective and applicable, to different sample matrices. In this article UA-ME and CA-ME, as the most important methods to enhance the efficiency of SPME and LPME, were reviewed and their different aspects were evaluated and compared. Comparison of different microextraction reinforcement approaches revealed that the CA-ME is the most effective method to increase the extraction efficiency, especially for the analysis of complicated solid matrices.
https://www.analchemres.org/article_42113_11ab729005ead4926c9177194478ca89.pdf
2017-06-01
105
126
10.22036/abcr.2016.59882.1114
Ultrasonic-assisted microextraction
Cooling-assisted microextraction
Solid-phase microextraction
Liquid-phase microextraction
Alireza
Ghiasvand
a_ghiasvand@yahoo.com
1
Department of Chemistry, Lorestan University, Khoramabad, Iran
LEAD_AUTHOR
Afagh
Nasirian
afagh_nasirian@yahoo.com
2
Department of Chemistry, Lorestan University, Khoramabad, Iran
AUTHOR
Samira
Koonani
konani.samira@gmail.com
3
Department of Chemistry, Lorestan University, Khoramabad, Iran
AUTHOR
Kolsoom
Nouriasl
nouriasl.k@gmail.com
4
Department of Chemistry, Lorestan University, Khoramabad, Iran
AUTHOR
[1] A.R. Ghiasvand, E. Mohagheghzadeh, Anal. Sci. 20 (2004) 917.
1
[2] J. Pawliszyn, S. Liu, Anal. Chem. 59 (1987) 1475.
2
[3] R.P. Belardi, J.B. Pawliszyn, Water Qual. Res. J. Can. 24 (1989) 179.
3
[4] C.L. Arthur, J. Pawliszyn, Anal. Chem. 62 (1990) 2145.
4
[5] A. Mehdinia, M.O. Aziz-Zanjani, Trends Anal. Chem. 42 (2013) 205.
5
[6] Z. Zhang, J. Pawliszyn, Anal. Chem. 65 (1993) 1843.
6
[7] A.R. Ghiasvand, S. Hajipour, Talanta 146 (2016) 417.
7
[8] Z. Zhang, J. Pawliszyn, Anal. Chem. 67 (1995) 34.
8
[9] M.A. Jeannot, F.F. Cantwell, Anal. Chem. 68 (1996) 2236.
9
[10] A.R. Ghiasvand, N. Heidari, P. Hashemi, Anal. Methods 6 (2014) 5992.
10
[11] S. Dadfarnia, A.M.H. Shabani, Anal. Chim. Acta 658 (2010) 107.
11
[12] C. Mahugo-Santana, Z. Sosa-Ferrera, M. Torres-Padrón, J.J. Santana-Rodríguez, Trends Anal. Chem. 30 (2011) 731.
12
[13] V. Andruch, M. Burdel, L. Kocúrová, J. Šandrejová, I.S. Balogh, Trends Anal. Chem. 49 (2013) 1.
13
[14] H. Xu, Y. Liao, J. Yao, J. Chromatogr. A 1167 (2007) 1.
14
[15] A.R. Ghiasvand, S. Hajipour, N. Heidari, Trends Anal. Chem. 77 (2016) 54.
15
[16] A.R. Ghiasvand, S. Hosseinzadeh, J. Pawliszyn, J. Chromatogr. A 1124 (2006) 35.
16
[17] F. Priego Capote, M.D. Luque de Castro, Anal. Bioanal. Chem. 387 (2007) 249.
17
[18] G. Wibetoe, D.T. Takuwa, W. Lund, G. Sawula, Fresen. J. Anal. Chem. 363 (1999) 46.
18
[19] H. Sereshti, Y.E. Heravi, S. Samadi, Talanta 97 (2012) 235.
19
[20] K. Vinodgopal, J. Peller, O. Makogon, P.V. Kamat, Water Res. 32 (1998) 3646.
20
[21] H. Wei, J. Yang, H. Zhang, Y. Shi, J. Sep. Sci. 37 (2014) 2349.
21
[22] P.L. Buldini, A. Mevoli, J.L. Sharma, Talanta 47 (1998) 203.
22
[23] G. Chen, J. Li, Z. Sun, S. Zhang, G. Li, C. Song, Y. Suo, J. You, Food Chem. 143 (2014) 97.
23
[24] G. Chen, J. Liu, M. Liu, G. Li, Z. Sun, S. Zhang, C. Song, H. Wang, Y. Suo, J. You, J. Chromatogr. A 1352 (2014) 8.
24
[25] H. Yan, H. Wang, X. Qin, B. Liu, J. Du, J. Pharm. Biomed. Anal. 54 (2011) 53.
25
[26] N. Jalbani, M. Soylak, Food Chem. 167 (2015) 433.
26
[27] J. Luque-Garcıa, M.L. De Castro, Trends Anal. Chem. 22 (2003) 41.
27
[28] M. Garcıa, J. Sanz, J. Chromatogr. A 918 (2001) 189.
28
[29] M. Russo, Chromatographia 39 (1994) 645.
29
[30] C. Lorenzo, A. Zalacain, G.L. Alonso, M.R. Salinas, J. Chromatogr. A 1114 (2006) 250.
30
[31] J.-F. Cavalli, X. Fernandez, L. Lizzani-Cuvelier, A.-M. Loiseau, J. Agric. Food Chem. 51 (2003) 7709.
31
[32] D.A. Lambropoulou, I.K. Konstantinou, T.A. Albanis, J. Chromatogr. A 1152 (2007) 70.
32
[33] J. Lee, J. Kang, D. Min, J. Food Sci. 68 (2003) 844.
33
[34] P. Kusch, G. Knupp, J. Sep. Sci. 25 (2002) 539.
34
[35] R. Batlle, A. Colmsjö, U. Nilsson, Fresen. J. Anal. Chem. 371 (2001) 514.
35
[36] R. Rial-Otero, E. Gaspar, I. Moura, J. Capelo, Talanta 71 (2007) 1906.
36
[37] M.H. Meshkatalsadat, S. Salahvarzi, R. Aminiradpoor, A. Abdollahi, Dig. J. Nanomater. Biostruct. 7 (2012) 637.
37
[38] F. Rezaei, M.-R.M. Hosseini, Anal. Chim. Acta 702 (2011) 274.
38
[39] L. Wang, L. Wang, J. Chen, W. Du, G. Fan, X. Lu, J. Chromatogr. A 1256 (2012) 9.
39
[40] P. Hashemi, M. Naderlou, M. Safdarian, A.R. Ghiasvand, Anal. Chem. Lett. 3 (2013) 92.
40
[41] F. Qiao, X. Zhang, M. Wang, Y. Kang, Chromatographia 72 (2010) 331.
41
[42] M.L. De Castro, F. Priego-Capote, Talanta 72 (2007) 321.
42
[43] K.-J. Huang, H. Wang, M. Ma, M.-L. Sha, H.-S. Zhang, J. Chromatogr. A 1103 (2006) 193.
43
[44] H. Yan, B. Liu, J. Du, K.H. Row, Analyst 135 (2010) 2585.
44
[45] H. Yan, B. Liu, J. Du, G. Yang, K.H. Row, J. Chromatogr. A 1217 (2010) 5152.
45
[46] H. Chen, P. Du, J. Chen, S. Hu, S. Li, H. Liu, Talanta 81 (2010) 176.
46
[47] X.Y. Jia, N.B. Li, H.Q. Luo, Chromatographia 71 (2010) 839.
47
[48] K.-J. Huang, C.-X. Jin, S.-L. Song, C.-Y. Wei, Y.-M. Liu, J. Li, J. Chromatogr. B 879 (2011) 579.
48
[49] H. Sereshti, Y. Izadmanesh, S. Samadi, J. Chromatogr. A 1218 (2011) 4593.
49
[50] J. Wu, B. Xiang, J. Xia, Microchim. Acta 166 (2009) 157.
50
[51] A.H. Panhwar, T.G. Kazi, H.I. Afridi, A.R. Abbasi, M.B. Arain, S.A. Arain, S.S. Arain, J. Ali, Anal. Methods 6 (2014) 8277.
51
[52] M. Molina-Calle, F. Priego-Capote, M.D.L. de Castro, Talanta 141 (2015) 150.
52
[53] H. Ebrahimzadeh, Z. Saharkhiz, M. Tavassoli, F. Kamarei, A.A. Asgharinezhad, J. Sep. Sci. 34 (2011) 1275.
53
[54] S. Tajik, M.A. Taher, Microchim. Acta 173 (2011) 249.
54
[55] A. Saleh, Y. Yamini, M. Faraji, M. Rezaee, M. Ghambarian, J. Chromatogr. A 1216 (2009) 6673.
55
[56] L. Wang, Z. Wang, H. Zhang, X. Li, H. Zhang, Anal. Chim. Acta 647 (2009) 72.
56
[57] L. Wang, D. Li, C. Bao, J. You, Z. Wang, Y. Shi, H. Zhang, Ultrason. Sonochem. 15 (2008) 738.
57
[58] C. Liu, Y. Zhu, Z. Zhou, J. Yang, F. Qi, Y. Pan, Anal. Chim. Acta 891 (2015) 203.
58
[59] J. Yang, H. Wei, X. Teng, H. Zhang, Y. Shi, Phytochem. Anal. 25 (2014) 178.
59
[60] L. Wang, Z. Wang, X. Li, H. Zhang, X. Zhou, H. Zhang, Chromatographia 71 (2010) 455.
60
[61] X. Li, L. Wang, Z. Wang, H. Zhang, R. Su, X. Xu, H. Zhang, J. Sep. Sci. 34 (2011) 1582.
61
[62] Y. Chen, J. Pawliszyn, Anal. Chem. 78 (2006) 5222.
62
[63] E. Carasek, J. Pawliszyn, J. Agric. Food Chem. 54 (2006) 8688.
63
[64] A.R. Ghiasvand, L. Setkova, J. Pawliszyn, Flav. Frag. J. 22 (2007) 377.
64
[65] E. Carasek, E. Cudjoe, J. Pawliszyn, J. Chromatogr. A 1138 (2007) 10.
65
[66] J.A. Koziel, S. Hosseinzadeh Haddadi, W. Koch, J. Pawliszyn, J. Sep. Sci. 32 (2009) 1975.
66
[67] S.H. Haddadi, V.H. Niri, J. Pawliszyn, Anal. Chim. Acta 652 (2009) 224.
67
[68] L. Sanchez-Prado, S. Risticevic, J. Pawliszyn, E. Psillakis, J. Photochem. Photobiol. A 206 (2009) 227.
68
[69] E. Martendal, E. Carasek, J. Chromatogr. A 1218 (2011) 367.
69
[70] E. Martendal, E. Carasek, J. Chromatogr. A 1218 (2011) 1707.
70
[71] R. Jiang, E. Carasek, S. Risticevic, E. Cudjoe, J. Warren, J. Pawliszyn, Anal. Chim. Acta 742 (2012) 22.
71
[72] J. Merib, G. Nardini, J.N. Bianchin, A.N. Dias, V. Simão, E. Carasek, J. Sep. Sci. 36 (2013) 1410.
72
[73] J. Guo, R. Jiang, J. Pawliszyn, J. Chromatogr. A 1307 (2013) 66.
73
[74] A.R. Ghiasvand, M. Pirdadeh-Beiranvand, Anal. Chim. Acta 900 (2015) 56.
74
[75] A.R. Ghiasvand, N. Heidari, Chromatographia 79 (2016) 1187.
75
[76] A.R. Ghiasvand, F. Yazdankhah, S. Hajipour, J. Se. Sci. 77 (2016) 54.
76
[77] L. Jiemin, J. Guibin, L. Jingfu, Z. Qunfang, Y. Ziwei, J. Sep. Sci. 26 (2003) 629.
77
[78] J. Liu, G. Jiang, Q. Zhou, J. Liu, M. Wen, Anal. Sci. 19 (2003) 1407.
78
[79] S.H. Haddadi, J. Pawliszyn, J. Chromatogr. A 1216 (2009) 2783.
79
[80] M.H. Banitaba, S.S. Hosseiny Davarani, S. Kazemi Movahed, J. Chromatogr. A 1325 (2014) 23.
80
[81] M. Moradi, M. Kaykhaii, A.R. Ghiasvand, S. Shadabi, A. Salehinia, Phytochem. Anal. 23 (2012) 379.
81
[82] M.H. Banitaba, S.S.H. Davarani, H. Ahmar, S.K. Movahed, J. Sep. Sci. 37 (2014) 1162.
82
[83] C. Achten, W. Püttmann, Environ. Sci. Technol. 34 (2000) 1359.
83
[84] C. Achten, A. Kolb, W. Püttmann, Fresen. J. Anal. Chem. 371 (2001) 519.
84
[85] K.-J. Chia, T.-Y. Lee, S.-D. Huang, Anal. Chim. Acta 527 (2004) 157.
85
[86] E. Fries, W. Püttmann, Anal. Bioanal. Chem. 386 (2006) 1497.
86
[87] L. Liao, J. Yang, Y. Wang, T. Sun, J. Jia, J. Chromatogr. A 1135 (2006) 1.
87
[88] X. Chai, J. Jia, T. Sun, Y. Wang, L. Liao, J. Environ. Sci. Health B 42 (2007) 629.
88
[89] Y.-C. Huang, Y.-S. Su, S. Muniraj, W. Zhang, J.-F. Jen, Anal. Bioanal. Chem. 388 (2007) 377.
89
[90] P. Hashemi, M. Abolghasemi, A. Fakhari, S.N. Ebrahimi, S. Ahmadi, Chromatographia 66 (2007) 283.
90
[91] H.C. Menezes, Z. de Lourdes Cardeal, J. Chromatogr. A 1218 (2011) 3300.
91
[92] L.C. Amorim, J.P. Carneiro, Z.L. Cardeal, J. Chromatogr. B 865 (2008) 141.
92
[93] H.C. Menezes, B.P. Paulo, N.T. Costa, Z.L. Cardeal, Microchem. J. 109 (2013) 93.
93
[94] H.C. Menezes, M.J.N. Paiva, R.R. Santos, L.P. Sousa, S.F. Resende, J.A. Saturnino, B.P. Paulo, Z.L. Cardeal, Microchem. J. 110 (2013) 209.
94
[95] R. Jiang, J. Pawliszyn, J. Chromatogr. A 1338 (2014) 17.
95
[96] R. Jiang, J. Pawliszyn, Trends Anal. Chem. 39 (2012) 245.
96
[97] A. Sarafraz-Yazdi, A. Amiri, Trends Anal. Chem. 29 (2010) 1-14.
97
[98] E. Aguilera-Herrador, R. Lucena, S. Cárdenas, M. Valcárcel, Anal. Chem. 80 (2008) 793.
98
[99] Y.-A. Shi, M.-Z. Chen, S. Muniraj, J.-F. Jen, J. Chromatogr. A 1207 (2008) 130.
99
[100] S.P. Huang, S.D. Huang, J. Chromatogr. A 1176 (2007) 19.
100
[101] M. Khajeh, Y. Yamini, J. Hassan, Talanta 69 (2006) 1088.
101
[102] S.P. Huang, P.S. Chen, S.-D. Huang, J. Chromatogr. A 1216 (2009) 4347.
102
[103] S. Chen, H. Peng, D. Wu, Y. Guan, J. Chromatogr. A 1217 (2010) 5883.
103
[104] M. Zhang, J. Bi, C. Yang, D. Li, X. Piao, J. Anal. Methods Chem. 2012 (2012) 1.
104
[105] M. Safdarian, P. Hashemi, M. Naderlou, J. Chromatogr. A 1244 (2012) 14.
105
[106] M. Rahimi, P. Hashemi, F. Nazari, Anal. Chim. Acta 826 (2014) 35.
106
[107] Y. Yamini, M. Hojjati, M. Haji-Hosseini, M. Shamsipur, Talanta 62 (2004) 265.
107
[108] G. Shen, H.K. Lee, Anal. Chem. 74 (2002) 648.
108
[109] L. Zhao, H.K. Lee, Anal. Chem. 74 (2002) 2486.
109
[110] X. Jiang, C. Basheer, J. Zhang, H.K. Lee, J. Chromatogr. A 1087 (2005) 289.
110
[111] M.-Y. Tsai, P.V. Kumar, H.-P. Li, J.-F. Jen, J. Chromatogr. A 1217 (2010) 1891.
111
[112] V.K. Ponnusamy, A. Ramkumar, J.-F. Jen, Microchim. Acta 179 (2012) 141.
112
[113] C. Yang, J. Qiu, C. Ren, X. Piao, X. Li, X. Wu, D. Li, J. Chromatogr. A 1216 (2009) 7694.
113
[114] C. Yang, X. Piao, J. Qiu, X. Wang, C. Ren, D. Li J. Chromatogr. A 1218 (2011) 1549.
114
[115] X. Piao, J. Bi, C. Yang, X. Wang, J. Wang, D. Li, Talanta 86 (2011) 142.
115
[116] C. Yang, J. Zhao, J. Wang, H. Yu, X. Piao, D. Li, J. Chromatogr. A 1300 (2013) 38.
116
[117] V. Miralles, A. Huerre, F. Malloggi, M.C. Jullien, Diagnostics 3 (2013) 33.
117
[118] J. El-Ali, P.K. Sorger, K.F. Jensen, Nature 442 (2006) 403.
118
[119] A.E. Sgro, P.B. Allen, D.T. Chiu, Anal. Chem. 79 (2007) 4845.
119
[120] P. Mosier-Boss, S. Lieberman, Anal. Chim. Acta 488 (2003) 15-23.
120
[121] F. Musshoff, D.W. Lachenmeier, L. Kroener, B. Madea, J. Chromatogr. A 958 (2002) 231.
121
[122] M.E. McComb, R.D. Oleschuk, E. Giller, H.D. Gesser, Talanta 44 (1997) 2137.
122
[123] R. Eisert, J. Pawliszyn, Anal. Chem. 69 (1997) 3140.
123
[124] M.A. Jochmann, M.P. Kmiecik, T.C. Schmidt, J. Chromatogr. A 1115 (2006) 208.
124
[125] K. Sieg, E. Fries, W. Püttmann, J. Chromatogr. A 1178 (2008) 178.
125
ORIGINAL_ARTICLE
Direct Chemiluminescence Determination of Oxymorphone Using Potassium Permanganate and Polyphosphoric Acid
Abstract A simple and sensitive chemiluminescence (CL) method was developed for direct quantification of oxymorphone, a µ opioid agonist that is approximately 10 times more potent than morphine. In this method potassium permanganate in polyphosphoric acid was used as CL reagent. Using this method, oxymorphone can be determined over the concentration ranges 13.5-337.8 ng mL-1 and 0.34-6.76 µg mL-1 with a sampling rate of 45 samples h−1. The limit of detection was 3.5 ng mL-1 (signal to noise =3) and the percent of relative standard deviations (in 9 replicate measurements) were 3.1% for 135.1 ng mL-1 and 3.6% for 1.4 µg mL-1 oxymorphone. The method is applied to human plasma and synthetic samples. The CL mechanism has been proposed using UV-Vis, fluorescence and CL spectra. In this study, detectability of oxymorphone in some other CL systems such as Ce(IV)-H2SO4, luminol-H2O2, Ru(phen)32+-Ce(IV) and permanganate-SO32- is investigated. CL intensities of twelve narcotics or related drugs were also investigated in the proposed CL system.
https://www.analchemres.org/article_44561_eecb1bdd6269a1efd19d464c66d94abd.pdf
2017-06-01
127
139
10.22036/abcr.2017.68970.1123
Chemiluminescence
Oxymorphone
Potassium permanganate
Polyphosphoric acid
Maryam
Koohsarian
mk_chemist@yahoo.com
1
Department of Chemistry, Golestan University, Gorgan, IR Iran
AUTHOR
Ali
Mokhtari
alimo58@yahoo.com
2
Department of Chemistry, Golestan University, Gorgan, IR Iran
LEAD_AUTHOR
[1] M.M. Fisher, D.G. Harle, B.A. Baldo, Clin. Rev. Allergy 9 (1991) 309.
1
[2] E. Prommer, Support. Care Cancer. 14 (2006) 109.
2
[3] M.E. Hale, H. Ahdieh, T. Ma, R. Rauck, O.E.S. Group, J. Pain 8 (2007) 175.
3
[4] P.W. Hellyer, J. Am. Vet. Med. Assoc. 221 (2002) 212.
4
[5] I.M. McIntyre, J.L. Sherrard, C.L. Nelson, J. Anal. Toxicol. 33 (2009) 615.
5
[6] A.C. Moffat, M.D. Osselton, B. Widdop, J. Watts, Clarke's Analysis of Drugs and Poisons, Pharmaceutical Press, 2011.
6
[7] Y. Yamini, A. Pourali, S. Seidi, M. Rezazadeh, Anal. Methods 6 (2014) 5554.
7
[8] G. Lam, R. Williams, C. Whitney, J. Chromatogr. B 413 (1987) 309.
8
[9] M. Neuvonen, P. Neuvonen, Ther. Drug Monit. 30 (2008) 333.
9
[10] W.B. Fang, M.R. Lofwall, S.L. Walsh, D.E. Moody, J. Anal. Toxicol. 37 (2013) 512.
10
[11] T. Dahn, J. Gunn, S. Kriger, A.R. Terrell, Clinical Applications of Mass Spectrometry: Methods and Protocols, Springer International Publishing, 2010, 411.
11
[12] F. Musshoff, J. Trafkowski, U. Kuepper, B. Madea, J. Mass Spectrom. 41 (2006) 633.
12
[13] W. Zha, L. Shum, J. Chromatogr. B 902 (2012) 116.
13
[14] E.D. Crum, K.M. Bailey, L.L. Richards-Waugh, D.J. Clay, M.A. Gebhardt, J.C. Kraner, J. Anal. Toxicol. special issue (2013) bkt077.
14
[15] F. Gaudette, A. Sirhan-Daneau, M. St-Onge, J. Turgeon, V. Michaud, J. Chromatogr. B 1008 (2016) 174.
15
[16] F. Musshoff, K. Lachenmeier, J. Trafkowski, B. Madea, F. Nauck, U. Stamer, Ther. Drug Monit. 29 (2007) 655.
16
[17] S.R. Edwards, M.T. Smith, J. Chromatogr. B 848 (2007) 264.
17
[18] E. Boström, B. Jansson, M. Hammarlund-Udenaes, U.S. Simonsson, Rapid Commun. Mass Spectrom. 18 (2004) 2565.
18
[19] R. Meatherall, J. Anal. Toxicol. 23 (1999) 177.
19
[20] S.G. McKinley, J.J. Snyder, E. Welsh, C.M. Kazarian, M.H. Jamerson, K.L. Klette, J. Anal. Toxicol. 31 (2007) 434.
20
[21] J.L. Adcock, P.S. Francis, N.W. Barnett, Anal. Chim. Acta 601 (2007) 36.
21
[22] D.C. Williams III, G.F. Huff, W.R. Seitz, Anal. Chem. 48 (1976) 1003.
22
[23] A. Mansouri, D.P. Makris, P. Kefalas, J. Pharm. Biomed. Anal. 39 (2005) 22.
23
[24] D.T. Bostick, D.M. Hercules, Anal. Lett. 7 (1974) 347.
24
[25] A. Mokhtari, A. Goudarzi, M. Benam, S.M. Langroodi, S. Karimmohammad, M. Keyvanfard, RSC Adv. 6 (2016) 5320.
25
[26] B.A. Gorman, P.S. Francis, N.W. Barnett, Analyst 131 (2006) 616.
26
[27] A. Mokhtari, M. Keyvanfard, I. Emami, Food Anal. Meth. 8 (2015) 2457.
27
[28] J.L. Adcock, N.W. Barnett, C.J. Barrow, P.S. Francis, Anal. Chim. Acta 807 (2014) 9.
28
[29] S. Srivastava, A. Adholeya, X.A. Conlan, D.M. Cahill, Plant Plant Food. Hum. Nutr. 71 (2016) 72.
29
[30] J.A. Murillo Pulgarín, L.F. García Bermejo, M.N. Sánchez García, Anal. Chim. Acta 602 (2007) 66.
30
[31] Y. Zhuang, X. Cai, J. Yu, H. Ju, J. Photochem. Photobiol.Chem. A 162 (2004) 457.
31
[32] K.A. George, M.S. Archer, L.M. Green, X.A. Conlan, T. Toop, Forensic Sci. Int. 193 (2009) 21.
32
[33] S. Parry, S.M. Linton, P.S. Francis, M.J. O’Donnell, T. Toop, J. Insect Physiol. 57 (2011) 62.
33
[34] L.A. Hill, C.E. Lenehan, P.S. Francis, J.L. Adcock, M.E. Gange, F.M. Pfeffer, N.W. Barnett, Talanta 76 (2008) 674.
34
[35] J.L. Adcock, P.S. Francis, K.M. Agg, G.D. Marshall, N.W. Barnett, Anal. Chim. Acta 600 (2007) 136.
35
[36] N.W. Barnett, B.J. Hindson, S.W. Lewis, Analyst 125 (2000) 91.
36
[37] Y.-F. Zhuang, S.-C. Zhang, J.-S. Yu, H.-X. Ju, Anal. Bioanal. Chem. 375 (2003) 281.
37
[38] J.A.M. Pulgarín, L.F.G. Bermejo, J.M.L. Gallego, M.N.S. García, Talanta 74 (2008) 1539.
38
[39] Y. He, J. Lu, M. Liu, J. Du, F. Nie, J. Anal. Toxicol. 29 (2005) 528.
39
[40] A. Campiglio, Analyst 123 (1998) 1053.
40
[41] A.A. Alwarthan, A. Townshend, Anal. Chim. Acta 185 (1986) 329.
41
[42] K.M. Agg, A.F. Craddock, R. Bos, P.S. Francis, S.W. Lewis, N.W. Barnett, J. Forensic Sci. 51 (2006) 1080.
42
[43] T.J. Christie, R.H. Hanway, D.A. Paulls, A. Townshend, Anal. Proc. Incl. Anal. Commun. 3 (1995) 91.
43
[44] OPANA-oxymorphone Hydrochloride Injection, Endo Pharmaceuticals Inc., 2013, http:// www.endo.com/File%20Library/Products/Prescribing%20Information/OPANA-Injection-prescribing-information.html, (accessed November, 2016).
44
[45] A. Mokhtari, Acta Chim. Slov. 61 (2016) Article Inpress, DOI: 10.17344/acsi.2015.2161.
45
[46] A. Mokhtari, M. Benam, M. Keyvanfard, M. Ghazaeian, Anal. Bioanal. Chem. Res. 3 (2016) 265.
46
[47] A. Mokhtari, M. Aaghamohammadhasan, Eurasian J. Anal. Chem. 12 (2017) 61.
47
[48] R.W. Abbott, A. Townshend, R. Gill, Analyst 111 (1986) 635.
48
[49] D. Zhang, Y. Ma, M. Zhou, L. Li, H. CHEN, Anal. Sci. 22 (2006) 183.
49
[50] N. Pinotsis, A.C. Calokerinos, W.R. Baeyens, Analyst 125 (2000) 1307.
50
[51] C.M. Hindson, P.S. Francis, G.R. Hanson, J.L. Adcock, N.W. Barnett, Anal. Chem. 82 (2010) 4174.
51
[52] M.R. Payán, M.Á.B. López, R. Fernández-Torres, M.V. Navarro, M.C. Mochón, Talanta 79 (2009) 911.
52
[53] J.L. Manzoori, M. Amjadi, J. Hassanzadeh, Microchim. Acta 175 (2011) 47.
53
[54] N. Barnett, C. Lenehan, S. Lewis, D. Tucker, K. Essery, Analyst 123 (1998) 601.
54
[55] G.N. Chen, F.X. Huang, X.P. Wu, Z.F. Zhao, J.P. Duan, Anal. Bioanal. Chem. 376 (2003) 873.
55
[56] I.B. Agater, R.A. Jewsbury, K. Williams, Anal. Commun. 33 (1996) 367.
56
[57] L. Wang, Chem. Anal. Warsaw 51 (2006) 211.
57
[58] L.N. Li, N.B. Li, H.Q. Luo, Anal. Sci. 21 (2005) 963.
58
[59] J.L. Adcock, P.S. Francis, N.W. Barnett, J. Fluoresc. 19 (2009) 867.
59
[60] J.L. Adcock, P.S. Francis, T.A. Smith, N.W. Barnett, Analyst 133 (2008) 49.
60
[61] T. Slezak, Z.M. Smith, J.L. Adcock, C.M. Hindson, N.W. Barnett, P.N. Nesterenko, P.S. Francis, Anal. Chim. Acta 707 (2011) 121.
61
ORIGINAL_ARTICLE
Modification of CoFe2O4 Magnetic Nanoparticles by Dopamine and Ascorbic Acid as Anchors
CoFe2O4 magnetic nanoparticles were modified by dopamine (DA) and ascorbic acid (AA) as anchors. Separation of the DA and AA using CoFe2O4 magnetic nanoparticles have been studied by investigating the effects of pH, concentration of the DA and AA, amount of adsorbents, contact time, ionic strength and temperature. The mechanism of adsorption was also studied. The adsorption of DA and AA to the CoFe2O4 magnetic nanoparticles could be described by Langmuir-type adsorption isotherms. The effective surface area of the CoFe2O4 nanoparticles was 53.55 m2/g and 109.81 m2/g, respectively, for DA and AA. The maximum adsorption capacities were 28.98 and 72.99 mg of enediol per gram of adsorbent for DA and AA, respectively. With the help of adsorption isotherm, thermodynamic parameters such as free energy, enthalpy, and entropy have been calculated. The adsorption of DA onto CoFe2O4 is exothermic, but the temperature effect was negligible for adsorption of AA. On the basis of pseudo-first-order and pseudo-second-order kinetic equations different kinetic parameters have been obtained. DA and AA can be desorbed from the CoFe2O4 using concentrated imidazole as an eluent.
https://www.analchemres.org/article_44741_30ca73fe67cf863c3ee6e7cee3f64801.pdf
1999-11-30
141
154
10.22036/abcr.2017.58422.1108
Magnetic nanoparticle
Adsorption
Dopamine
Ascorbic acid
Maryam
Ghaemi
mghaemi@inio.ac.ir
1
Iranian National Institute for Oceanography and Atmospheric Science
LEAD_AUTHOR
Ghodratollah
Absalan
absalan@susc.ac.ir
2
Professor Massoumi Laboratory, Department of Chemistry, Faculty of Sciences, Shiraz University, Shiraz 71454, Iran
AUTHOR
Tayebe
pourshamsi
tayebepoorshamsi@yahoo.com
3
Professor Massoumi Laboratory, Department of Chemistry, Faculty of Sciences, Shiraz University, Shiraz 71454, Iran
AUTHOR
[1] R.W. Siegel, Sci. Am. 275 (1996) 74.
1
[2] Y.W. Jun, J.H. Lee, J. Cheon, Angew. Chem. Int. Ed. 47 (2008) 5122.
2
[3] M.M. Lin, D.K. Kim, A.J. El Haj, J. Dobson, IEEE Trans. Nanobioscience 7 (2008) 298.
3
[4] M. Namdeo, S. Saxena, R. Tankhiwale, M. Bajpai, Y. Mohan, S. Bajpai, J. Nanosci. Nanotechnol. 8 (2008) 3247.
4
[5] Y.W. Jun, Y.M. Huh, J.S. Choi, J.H. Lee, H.T. Song, S. Kim, S. Kim, S. Yoon, K.S. Kim, J.S. Shin, J. Am. Chem. Soc. 127 (2005) 5732.
5
[6] H.M. Reinl, M. Peller, M. Hagmann, P. Turner, R.D. Issels, M. Reiser, Imaging 23 (2005) 1017.
6
[7] G. Kenning, R. Rodriguez, V. Zotev, A. Moslemi, S. Wilson, L. Hawel, C. Byus, J. Kovach, Rev. Sci. Instrum. 76 (2005) 014303.
7
[8] D. Wang, J. He, N. Rosenzweig, Z. Rosenzweig, Nano Lett. 4 (2004) 409.
8
[9] M. Ghaemi, G. Absalan, J. Iran. Chem. Soc. 12 (2015) 1.
9
[10] M. Ghaemi, G. Absalan, Microchim. Acta 181 (2014) 45.
10
[11] M. Karimi, A.M. Shabani, S. Dadfarnia, J. Braz. Chem. Soc. 27 (2016) 144.
11
[12] M. Ghaemi, G. Absalan, L. Sheikhian, J. Iran. Chem. Soc. 11 (2014) 1759.
12
[13] C. Sun, J.S. Lee, M. Zhang, Adv. Drug Delivery Rev. 60 (2008) 1252.
13
[14] A. Dyal, K. Loos, M. Noto, S.W. Chang, C. Spagnoli, K.V. Shafi, A. Ulman, M. Cowman, R.A. Gross, J. Am. Chem. Soc. 125 (2003) 1684.
14
[15] L.X. Chen, T. Liu, M.C. Thurnauer, R. Csencsits, T. Rajh, J. Phys. Chem. B 106 (2002) 8539.
15
[16] C. Xu, K. Xu, H. Gu, R. Zheng, H. Liu, X. Zhang, Z. Guo, B. Xu, J. Am. Chem. Soc. 126 (2004) 9938.
16
[17] E. Amstad, A.U. Gehring, H. Fischer, V.V. Nagaiyanallur, G. Hähner, M. Textor, E. Reimhult, J. Phys. Chem. C 115 (2010) 683.
17
[18] E. Amstad, T. Gillich, I. Bilecka, M. Textor, E. Reimhult, Nano lett. 9 (2009) 4042.
18
[19] M.D. Shultz, J.U. Reveles, S.N. Khanna, E.E. Carpenter, J. Am. Chem. Soc. 129 (2007) 2482.
19
[20] H. Gu, Z. Yang, J. Gao, C. Chang, B. Xu, J. Am. Chem. Soc. 127 (2005) 34.
20
[21] [21] J. Xie, C. Xu, N. Kohler, Y. Hou, S. Sun, Adv. Mater. 19 (2007) 3163.
21
[22] J. Xie, C. Xu, Z. Xu, Y. Hou, K.L. Young, S. Wang, N. Pourmand, S. Sun, Chem. Mater. 18 (2006) 5401.
22
[23] T. Rajh, L. Chen, K. Lukas, T. Liu, M. Thurnauer, D. Tiede, J. Phys. Chem. B 106 (2002) 10543.
23
[24] H. Lee, S.M. Dellatore, W.M. Miller, P.B. Messersmith, Science 318 (2007) 426.
24
[25] A. Liu, I. Honma, H. Zhou, Electrochem. Commun. 7 (2005) 233.
25
[26] M. Gharagozlou, J. Alloys Compd. 486 (2009) 660.
26
[27] J. Akl, T. Ghaddar, A. Ghanem, H. El-Rassy, J. Mol. Catal. A: Chem. 312 (2009) 18.
27
[28] B.D. Bath, H.B. Martin, R.M. Wightman, M.R. Anderson, Langmuir 17 (2001) 7032.
28
[29] K. Syres, A. Thomas, F. Bondino, M. Malvestuto, M. Gratzel, Langmuir 26 (2010) 14548.
29
[30] C. Chinnasamy, B. Jeyadevan, O. Perales-Perez, K. Shinoda, K. Tohji, A. Kasuya, IEEE Trans. Magn. 38 (2002) 2640.
30
[31] M.A.M. Salleh, D.K. Mahmoud, W.A.W.A. Karim, A. Idris, Desalination 280 (2011) 1.
31
[32] T. Rajh, J. Nedeljkovic, L. Chen, O. Poluektov, M. Thurnauer, J. Phys. Chem. B 103 (1999) 3515.
32
[33] [33] P. Redfern, P. Zapol, L. Curtiss, T. Rajh, M. Thurnauer, J. Phys. Chem. B 107 (2003) 11419.
33
[34] L.G. Rego, V.S. Batista, J. Am. Chem. Soc. 125 (2003) 7989.
34
[35] B. Baeyens, M.H. Bradbury, J. Contam. Hydrol. 27 (1997) 199.
35
[36] S.M. Yu, A. Ren, C.L. Chen, Y. Chen, X. Wang, Appl. Radiat. Isotopes 64 (2006) 455.
36
[37] Z. Chen, J. He, L. Chen, S. Lu, J. Radioanal. Nucl. Chem. 307 (2016) 1093.
37
[38] I. Langmuir, J. Am. Chem. Soc. 40 (1918) 1361.
38
[39] K. Hall, L. Eagleton, A. Acrivos, T. Vermeulen, Ind. Eng. Chem. Fund. 5 (1966) 212.
39
[40] H. Freundlich, J. Phys. Chem. 57 (1906) 385.
40
[41] S. Lowell, J.E. Shields, M.A. Thomas, M. Thommes, Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density, Springer Science & Business Media, 2012.
41
[42] A. Tóth, A. Törőcsik, E. Tombácz, E. Oláh, M. Heggen, C. Li, E. Klumpp, E. Geissler, K. László, J. Colloid Interface Sci. 364 (2011) 469.
42
[43] S. Lagergren, K. Sven. Vetensk.Akad. Handl. 24 (1898) 1.
43
[44] Y.-S. Ho, G. McKay, Chem. Eng. J. 70 (1998) 115.
44
[45] C. Wang, R. Yuan, Y. Chai, S. Chen, F. Hu, M. Zhang, Anal. Chim. Acta 741 (2012) 15.
45
ORIGINAL_ARTICLE
Multi-walled Carbon Nanotubes/Ionic Liquid Nanocomposite Modified Carbon-ceramic Electrode: Electrochemistry and Measurement of Tryptophan in the Presence of Uric Acid
In the present work, an efficient modified carbon-ceramic electrode by multi-walled carbon nanotubes/ionic liquid nanocomposite (MWCNTs/IL/CCE) was prepared through a simple and repeatable procedure. The introduced modified electrode was used for the study of the electrochemical behaviour and determination of tryptophan (Trp) in the presence of uric acid (UA) using cyclic voltammetry (CV), differential pulse voltammetry (DPV) and amperometry techniques. The MWCNTs/IL/CCE exhibited high electrocatalytic activity toward the oxidation of Trp in phosphate buffer solution (pH 7.0) which led to produce an anodic peak at about 0.67 V vs. saturated calomel electrode. The influential parameters such as pH, amount and ratio of MWCNTs/IL in the nanocomposite modifier on the electrocatalytic activity of the MWCNTs/IL/CCE were studied and optimized. Under the optimum conditions, the anodic peak current in DPV method is linear for the Trp concentrations in the ranges of 5×10-7 M to 7×10-5 M with a correlation coefficient of 0.998 and detection limit of 3.2×10-7 M (S/N=3). The relative standard deviation of the anodic peak current obtained for a 5.0×10-5 M Trp solution was 2.2% (n=6). Finally, DPV method was applied for simultaneous determination of Trp and UA, which demonstrates the applicability of the present modified electrode.
https://www.analchemres.org/article_44747_5282313ab5e5aa625b11ccd29b9f0ff7.pdf
2017-06-01
155
169
10.22036/abcr.2017.64667.1120
Multi-walled carbon nanotubes
Ionic Liquid
Nanocomposite
tryptophan
Uric Acid
Simultaneous determination
Modified electrode
Biuck
Habibi
b.habibi@azaruniv.edu
1
Electroanalytical Chemistry Laboratory, Department of Chemistry, Faculty of Sciences, Azarbaijan Shahid Madani University, Tabriz 53714-161, Iran
LEAD_AUTHOR
Zahra
Ayazi
2
Electroanalytical Chemistry Laboratory, Department of Chemistry, Faculty of Sciences, Azarbaijan Shahid Madani University, Tabriz 53714-161, Iran
AUTHOR
Maryam
Dadkhah
3
Electroanalytical Chemistry Laboratory, Department of Chemistry, Faculty of Sciences, Azarbaijan Shahid Madani University, Tabriz 53714-161, Iran
AUTHOR
[1] M.H. Fernstrom, J.D. Fernstrom, Life Sci. 57 (1995) PL97.
1
[2] W. Lian, D.J. Ma, X.U. Xu, Y. Chen, Y.L. Wu, J. Digest. Dis. 13 (2012) 100.
2
[3] M.E. Soto, A.M. Ares, J. Bernal, M.J. Nozal, J.L. Bernal, J. Chromatogr. A 1218 (2011) 7592.
3
[4] J. Galba, A. Michalicova, V. Parrak, M. Novak, A. Kovac, J. Pharmaceut. Biomed. Anal. 117 (2016) 85.
4
[5] A. Zinellu, S. Sotgia, L. Deiana, G. Talanas, P. Terrosu, C. Carru, J. Sep. Sci. 35 (2012) 1146.
5
[6] Y. Takagai, S. Igarashi, Chem. Pharm. Bull. 51 (2003) 373.
6
[7] M. Zhao, M.-F. Zhou, H. Feng, X.-X. Cong, X.-L. Wang, Chromatographia 79 (2016) 911.
7
[8] A.J. Lewis, P.J. Holden, R.C. Ewan, D.R. Zimmerman, J. Agricultural and Food Chem. 24 (1976) 1081.
8
[9] T. Sasaki, B. Abrams, B.L. Horecker, Anal. Biochem.
9
65 (1975) 396.
10
[10] Y. Wu, S. Han, Anal. Chem.: An Indian J. 16 (2016) 1.
11
[11] H. Qiu, C. Luo, M. Sun, F. Lu, L. Fan, X. Li, Talanta 98 (2012) 226.
12
[12] F. Wu, B. Tong, Q. Zhang, Anal. Sci. 27 (2011) 529.
13
[13] C.-J. Lee, J. Yang, Anal. Biochem. 359 (2006) 124.
14
[14] M.M. Yust, J. Pedroche, J. Girón-Calle, J. Vioque, F. Millán, M. Alaiz, Food Chem. 85 (2004) 317.
15
[15] A. Babaei, M. Zendehdel, B. Khalilzadeh, A. Taheri, Colloid Surface B: Biointerfaces 66 (2008) 226.
16
[16] C. Wang, R. Yuan, Y. Chai, S. Chen, F. Hu, M. Zhang, Anal. Chim. Acta 741 (2012) 15.
17
[17] S. Mao, W. Li, Y. Long, Y. Tu, A. Deng, Anal. Chim. Acta 738 (2012) 35.
18
[18] S.M. Ghoreishi, M. Behpour, F. Saeidinejad, Anal. Methods 4 (2012) 2447.
19
[19] H. Beitollahi, A. Mohadesi, S.K. Mahani, H.K. Maleh, A. Akbari, Turk. J. Chem. 36 (2012) 526.
20
[20] K.-Q. Deng, J.-h. Zhou, X.-F. Li, Colloid Surface B:
21
Biointerfaces 101 (2012) 183.
22
[21] W. Li, C. Li, Y. Kuang, P. Deng, S. Zhang, J. Xu, Microchim. Acta 176 (2012) 455.
23
[22] M.B. Gholivand, A. Pashabadi, A. Azadbakht, S. Menati, Electrochim. Acta 56 (2011) 4022.
24
[23] A. Safavi, S. Momeni, Electroanalysis 22 (2010) 2848.
25
[24] Q. Sheng, R. Liu, H. Zhang, J. Zheng, J. Iran. Chem. Soc. 13 (2016) 1189.
26
[25] M. Mazloum-Ardakani, Z. Taleat, H. Beitollahi, H. Naeimi, J. Iran. Chem. Soc. 7 (2010) 251.
27
[26] B.K. Price, J.L. Hudson, J.M. Tour, J. Am. Chem. Soc. 127 (2005) 14867.
28
[27] R.T. Kachoosangi, M.M. Musameh, I. Abu-Yousef, J. M. Yousef, S.M. Kanan, L. Xiao, S.G. Davies, A. Russell, R.G. Compton, Anal. Chem. 81 (2008) 435.
29
[28] M. Rahimi-Nasrabadi, A. Khoshroo, M. Mazloum-Ardakani, Sensor Actuat. B: Chem. 240 (2017) 125.
30
[29] F. Jalali, M. Ardeshiri, Mater. Sci. Engin. C 69 (2016) 276.
31
[30] M. Fouladgar, Sensor Actuat. B: Chem. 230 (2016) 456.
32
[31] S. Cheraghi, M.A. Taher, J. Mol. Liquids 219 (2016) 1023.
33
[32] H. Rajabi, M. Noroozifar, M. Khorasani-Motlagh, Anal. Bioanal. Electrochem. 8 (2016) 522.
34
[33] T. Fukushima, A. Kosaka, Y. Ishimura, T. Yamamoto, T. Takigawa, N. Ishii, T. Aida, Science 300 (2003) 2072.
35
[34] M.R. Majidi, M.H. Pournaghi-Azar, R. Fadakar Bajeh Baj, A. Naseri, Int. J. Environ. Anal. Chem. 96 (2016) 50.
36
[35] R. Faramarzi, A.R Taheri, M. Roushani, Anal. Bioanal. Electrochem. 7 (2015) 666.
37
[36] N. Nasirizadeh, Z. Shekari, M. Dehghani, S. Makarem, J. Food Drug Anal. 24 (2016) 406.
38
[37] S.M. Ghoreishi, M. Behpour, S. Mousavi, A. Khoobi, F.S. Ghoreishi, Anal. Methods 7 (2015) 466.
39
[38] B. Jahanshahi, J. Raoof, M. Amiri-Aref, R. Ojani, J. Chilean Chem. Soc. 59 (2015) 2692.
40
[39] O. Lev, Z. Wu, S. Bharathi, V. Glezer, A. Modestov, J. Gun, L. Rabinovich, S. Sampath, Chem. Mater. 9 (1997) 2354.
41
[40] B. Habibi, M. Jahanbakhshi, M.H. Pournaghi-Azar, Microchim. Acta 177 (2011) 185.
42
[41] B. Habibi, M. Abazari, M.H. Pournaghi-Azar, Colloid Surface B: Biointerfaces 114 (2014) 89.
43
[42] B. Habibi, M. Jahanbakhshi, M. Abazari, J. Iran. Chem. Soc. 11 (2014) 511.
44
[43] B. Habibi, M. Jahanbakhshi, Electrochim. Acta 118 (2014) 10.
45
[44] B. Habibi, M.H. Pournaghi-Azar, Electrochim. Acta 55 (2010) 5492.
46
[45] B. Habibi, M. Jahanbakhshi, M.H. Pournaghi-Azar, Electrochim. Acta 56 (2011) 2888.
47
[46] X. Liu, Z. Ding, Y. He, Z. Xue, X. Zhao, X. Lu, Colloid Surface B: Biointerfaces 79 (2010) 27.
48
[47] H. Liu, P. He, Z. Li, C. Sun, L. Shi, Y. Liu, G. Zhu, J. Li, Electrochem. Commun. 7 (2005) 1357.
49
[48] L.I.N. Tomé, V.T.R. Catambas, A.R.R. Teles, M.G. Freire, I.M. Marrucho, J.O.A.P. Coutinho, Sep. Purif. Technol. 72 (2010) 167.
50
[49] S. Shahrokhian,L. Fotouhi, Sensor Actuat. B: Chem. 123 (2007) 942.
51
[50] J. Li, D. Kuang, Y. Feng, F. Zhang, Z. Xu, M. Liu, D. Wang, Biosens. Bioelectron. 42 (2013) 198.
52
[51] W. Huang, G. Mai, Y. Liu, C. Yang, W. Qua, J. Nanosci. Nanotechnol. 4 (2004) 423.
53
[52] X. Liu, L. Luo, Y. Ding, D. Ye, Bioelectrochemistry 82 (2011) 38.
54
[53] K.-J. Huang, C.-X. Xu, J.-Y. Sun, W.-Z. Xie, L. Peng, Anal. Lett. 43 (2009) 176.
55
[54] Y. Guo, S. Guo, Y. Fang, S. Dong, Electrochim. Acta 55 (2010) 3927.
56
[55] Y. Liu, L. Xu, Sensors 7 (2007) 2446.
57
[56] J.-B. Raoof, R. Ojani, M. Baghayeri, Sensor Actuat. B: Chem. 143 (2009) 261.
58
[57] X. Tang, Y. Liu, H. Hou, T. You, Talanta 80 (2010) 2182.
59
[58] B. Fang, Y. Wei, M. Li, G. Wang, W. Zhang, Talanta 72 (2007) 1302.
60
ORIGINAL_ARTICLE
Combination of Experimental Design and Desirability Function as a Genuine Method to Achieve Common Optimal Conditions for the Adsorption of Pb(II) and Cu(II) onto the Poplar Tree Leaves: Equilibrium, Kinetic and Thermodynamic Studies
In this study, the ashes of poplar tree leaves are applied as an efficient, accessible and inexpensive biosorbent for the removal of heavy metals Pb2+ and Cu+2 in aqueous solutions. In the adsorption processes, the success of the ions removal highly depends on the level of several experimental factors such as pH, contact time, adsorbent dosage and temperature. Therefore, a genuine statistical experiment design method is required to achieve a common experimental conditions where both ions have been removed from aqueous solutions to a great degree. Here, this common optimal conditions are obtained by the combination of experimental design and desirability function methods. For a mixture of Pb2+ and Cu+2, the following optimal conditions were achieved: pH of 5.4, contact time of 23 min, adsorbent dosage of 0.14 g, and temperature of 280C; at 150 mg L-1 of Pb2+ and 120 mg L-1 Cu2+. The removal efficiencies of Pb2+ and Cu+2 were 92.8% and 94.9%, respectively, which verified the applicability of this biosorbent for the ions removal. Moreover, the equilibrium and kinetic behavior of the adsorption processes are investigated and then thermodynamic parameters, ΔG0(Kj mol-1), ΔH(Kj mol-1)0, and ΔS0 (Kj mol-1), are evaluated which reveal that both processes are endothermic and spontaneous.
https://www.analchemres.org/article_44748_ade2e04a2148f1fc9f91d6cfe3ea4591.pdf
2017-03-01
171
187
10.22036/abcr.2016.67517.1122
Desirability function
Biosorption
heavy metals
Kinetic
thermodynamic parameters
Salma
Jadali
sadaf.jad@gmail.com
1
Faculty of Chemistry, Semnan University, Semnan, Iran.
AUTHOR
S. Maryam
Sajjadi
sajjadi@semnan.ac.ir
2
Faculty of Chemistry, Semnan University, Semnan, Iran
LEAD_AUTHOR
Hassan
Zavvar Mousavi
hzmousavi@semnan.ac.ir
3
Faculty of Chemistry, Semnan University, Semnan, Iran
AUTHOR
Maryam
Rajabi
mrajabi@ymail.com
4
Faculty of Chemistry, Semnan University, Semnan, Iran
AUTHOR
[1] X. Tang, Q. Zhang, Z. Liu, K. Pan, Y. Dong, Y. Li, J. Mol. Liq. 199 (2014) 401.
1
[2] B. Dumitru, B. Laura, Bioresour. Technol. 129 (2013) 374.
2
[3] W. Meng-Wei, K. Chi-Chuan, B.D. Rogel, M.L.P. Dalida, Carbohydr. Polym. 80 (2010) 891.
3
[4] F. Boudrahem, A. Soualah, F. Aissani-Benissad, J. Chem. Eng. Data 56 (2011) 1946.
4
[5] Q. Zhong, Q.Y. Yue, Q. Li, B.Y. Gao, X. Xu, Carbohydr. Polym. 111 (2014) 788.
5
[6] I. Anastopoulos, G.Z. Kyzas, J. Mol. Liq. 209 (2015) 77.
6
[7] Q. Chang, G. Wang, Chem. Eng. Sci. 62 (2007) 4636.
7
[8] B. Alyüz, S. Veli, J. Hazard. Mater. 167 (2009) 482.
8
[9] A. Shafaei, M. Rezayee, M. Arami, M. Nikazar, Desal. 260 (2010) 23.
9
[10] D. Riazatia, B. Aibaghi-Esfahani, M. Fayazi, M. Ghanei-Motlagh, Anal. Bioanal. Chem. Res. 2 (2015) 1.
10
[11] G.E.P. Box, N.R. Draper, Empirical Model-Building and Response Surfaces, Wiley, New York, 1987.
11
[12] S.D. Brown, R. Tauler, B. Walczak, Comprehensive Chemometrics Chemical and Biochemical Data
12
Analyses 1 (2009) 346.
13
[13] E.C. Harrington, Indust. Qual. Cont. 1 (1965) 494.
14
[14] G. Derringer, R. Suich, Qual. Technol. 12 (1980) 214.
15
[15] M. Anbia, M. Khazaei, J. Chem. Chem. Eng. 33 (2014) 29.
16
[16] N. Kim, M. Park, D. Park, Bioresour. Technol. 175 (2015) 629.
17
[17] M. Iqbal, R.G.J. Edyvean, Miner. Eng. 17 (2004) 217.
18
[18] J.J. Dongarra, C.B. Moler, J.R. Bunch, G.W. Stewart, Linpak User’s Guid, e, Chap. 9, Siam, 1979.
19
[19] A. Naseri, S.R. Nabavi, M. Pirouzmand, S. Sheykhizadeh Mizan, Computer Application in Chemistry. University of Tabriz, Iran, 2016.
20
[20] N. Kanagathara, P. Shenbagarajan, C.E. Jeyanthi, M. Thirunavukkarasu, Int. J. Pharm. Bio. Sci. 1 (2011) 52.
21
[21] J. Wang, C. Chen, Biotechnol. Adv. 27 (2009) 195.
22
[22] I. Langmuir, J. Am. Chem. Soc. 40 (1918) 1361.
23
[23] T.M. Alslaibi, I. Abustan, M.A. Ahmad, A.A. Foul, J. Chem. Technol. Biotechnol. 88 (2013) 2141.
24