Determination of Rhodium(III) Ions by Flame Atomic Absorption Spectrometry after Preconcentration with Modified Magnetic Activated Carbon

Document Type: Research Paper

Authors

1 Shahid Bahonar University of Kerman

2 Islamic Azad University

Abstract

A new method for analysis of trace amount of Rh(III) ions by magnetic activated carbon modified with 2,3,5,6-tetra(2-pyridyl)pyrazine (MAC/TPPZ) as the magnetic sorbent has been proposed. The proposed adsorbent was found to be advantageous over conventional solid phase extraction (SPE) in terms of operational simplicity and low time-consuming. The experimental parameters affecting the extraction/preconcentration and determination of the analyte were systematically examined. In order to investigate the selectivity of this magnetic sorbent, the effect of a variety of ions on preconcentration and recovery of Rh(III) ions were also investigated. Under optimum conditions, the calibration graph was linear for the concentration range of 0.8-650 µg l-1. The limit of detection (LOD, 3Sb/m) and the relative standard deviation (RSD, n = 8, c = 50 µg l-1) were 0.1 µg l-1 and 3.6%, respectively. The maximum sorption capacity of the adsorbent for rhodium was found to be 21.6 mg g-1. The presented procedure was applied to monitoring rhodium in water and synthetic samples.

Keywords

References

[1] M. Ghaedi, M. Montazerozohori, H. Saidi, M. Rajabi, Anal. Bioanal. Chem. Res., 1 (2014) 50.

[2] T. Madrakian, B. Zadpour, M. Ahmadi, A. Afkhami, J. Iran. Chem. Soc., 12 (2015) 1235.

[3] M.A. Kassem, A.S. Amin, Spectrochim. Acta, A, 136, Part C (2015) 1955.

[4] X. Chang, X. Luo, G. Zhan, Z. Su, Talanta, 39 (1992) 937.

[5] M. Resano, M.d.R. Flórez, I. Queralt, E. Marguí, Spectrochim. Acta, Part B, 105 (2015) 38.

[6] C.B. Ojeda, F.S. Rojas, Talanta, 71 (2007) 1.

[7] S. Ghaseminezhad, D. Afzali, M.A. Taher, Talanta, 80 (2009) 168.

[8] M. Kauppinen, K. Smolander, Anal. Chim. Acta, 285 (1994) 45.

[9] E. Molaakbari, A. Mostafavi, D. Afzali, J. Hazard. Mater., 185 (2011) 647.

[10] A. Jaree, N. Khunphakdee, J. Ind. Eng. Chem., 17 (2011) 243.

[11] D. Afzali, A. Mostafavi, H. Beitollah, Microchim. Acta, 171 (2010) 97.

[12] D. Riazati, B. Aibaghi-Esfahani, M. Fayazi, M. Ghanei-Motlagh, Anal. Bioanal. Chem. Res., 2 (2015) 1.

[13] H.R. Rajabi, M. Shamsipur, M.M. Zahedi, M. Roushani, Chem. Eng. J., 259 (2015) 330.

[14] M. Faraji, Y. Yamini, S. Shariati, J. Hazard. Mater., 166 (2009) 1383.

[15] F. Shakerian, S. Dadfarnia, A.M.H. Shabani, Food Chem., 134 (2012) 488.

[16] H. Ebrahimzadeh, E. Moazzen, M.M. Amini, O. Sadeghi, Chem. Eng. J., 215–216 (2013) 315.

[17] M.H. Mashhadizadeh, Z. Karami, J. Hazard. Mater., 190 (2011) 1023.

[18] V. Khalili-Fard, K. Ghanemi, Y. Nikpour, M. Fallah-Mehrjardi, Anal. Chim. Acta, 714 (2012) 89.

[19] M. Ghaedi, F. Ahmadi, M. Soylak, J. Hazard. Mater., 147 (2007) 226.

[20] R. Li, Q. He, Z. Hu, S. Zhang, L. Zhang, X. Chang, Anal. Chim. Acta, 713 (2012) 136.

[21] K. Ghanemi, Y. Nikpour, O. Omidvar, A. Maryamabadi, Talanta, 85 (2011) 763.

[22] R. Liu, P. Liang, J. Hazard. Mater., 152 (2008) 166.

[23] T. Daşbaşı, Ş. Saçmacı, A. Ülgen, Ş. Kartal, Food Chemistry, 174 (2015) 591.

[24] N. Wang, J. Wang, Y. Liao, S. Shao, Talanta, 151 (2016) 1.

[25] V.A. Lemos, L.S.G. Teixeira, M.d.A. Bezerra, A.C.S. Costa, J.T. Castro, L.A.M. Cardoso, D.S. de Jesus, E.S. Santos, P.X. Baliza, L.N. Santos, Appl. Spectrosc. Rev., 43 (2008) 303.

[26] A.M. Starvin, T.P. Rao, Talanta, 63 (2004) 225.

[27] H. Abdolmohammad-Zadeh, Z. Talleb, Talanta, 134 (2015) 387.

[28] M. Fayazi, M.A. Taher, D. Afzali, A. Mostafavi, M. Ghanei-Motlagh, Mater. Sci. Eng., C, 60 (2016) 365.

[29] J. Sun, Q. Liang, Q. Han, X. Zhang, M. Ding, Talanta, 132 (2015) 557.

[30] H.A. Omar, H. Moloukhia, J. Hazard. Mater., 157 (2008) 242.

[31] E. Darezereshki, M. Ranjbar, F. Bakhtiari, J. Alloys Compd., 502 (2010) 257.

[32] R. Nie, X. Chang, Q. He, Z. Hu, Z. Li, J. Hazard. Mater., 169 (2009) 203.

[33] F. Sánchez Rojas, C.B. Ojeda, J.M.C. Pavón, Talanta, 64 (2004) 230.

[34] I.A. Kovalev, L.V. Bogacheva, G.I. Tsysin, A.A. Formanovsky, Y.A. Zolotov, Talanta, 52 (2000) 39.

[35] M.A. Taher, Anal. Chim. Acta, 382 (1999) 339.

[36] R.K. Dubey, A. Bhalotra, M.K. Gupta, B.K. Puri, Microchem. J., 58 (1998) 117.

Analytical and Bioanalytical Chemistry Research

Volume 3, Issue 1
Spring 2016
Pages 87-99

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